浙江省2021-2022学年高考化学一模试卷含解析

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+2H++Cl-22ஹghiᑴᜓlmnḄgho᝞qᡠcEᜳᢝouᶍwP஺Xᑡxyz`aḄfEP{|{l⏚~ₐḄᔠᱥA.Ḅeᱥᙳᒴஹ᧕ᑴB.{⏚ஹ{l⏚~nᔠᔣ{l⏚Wᐭ{⏚ᓾiᡠᔠᱥᐭnWC.ᘤaḄᵨf¡¢ᧇḄᑭᵨ᳛D.e¦ᐰ¨ᵨᘤaஹb©ªᑮ¬3ஹᔣNa2c03ஹNaHCChᔠUVW⌲¯ᐭ°±⏚ᡂ³´ḄRµ±⏚ᐭRḄ¶ᓄᐵ¸᝞qᡠcᑣXᑡZ[ºᙠ»ḄUVWDC_ᜧRᐳ½ḄfEPA.a»ḄUVWNa\OH\SO2\NO43B.b»ḄUVWK\Ca2\H\Cl"

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ᨵ0.2mole-23456789ᣚ;ḄH*Ḅ<ᦪ(0.2NAD.A᩽Ḅᵯ᩽+,-(CY^-OH+H*+2e-—Cl-+6ஹᕜ@⊤
ᨵ᝞ᡠḄᐗCᑡDEḄnJ47.87JA.47.87FGᨬIḄJ8ḄK87LB.J8ḄMMNᐳᨵ10<ᵯ8C.Pᵯ8᪀RSJTUVWXᐗCD.22(J8Ḅ7Lᦪ7ஹ2019Y9ᨴ25[ᐰ]^_ᜧabc——ᓅfᜧᐶh▭jk-ᢗm஺ᑡKᐵḄpqA.jᩰstuᡠᵨwxTUᔠzᩞᧇB.stu}ᵨḄ~ᴻjzTᩞᧇC.stuᵨḄ◞◫ᵫwKᡂTURjᩞᧇ

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—^ZH—CFj—CF—22CF3-CJt-CFi-^-CFi-CF-A.&B.CH2=CF2CF2=CFCF3CH2=CF2-CF=CTDCF2=CF-CH2=CFc•CFoAF310ஹᑡḄA.ÁᔣO.lmoM/iḄÏ⏚ÐÑ
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cH+/cCH3COOH%B.+,N2g+3H2g=2NH3gAH<0ÔÕ⊝×ØÙÁG+,᳛Ûᜧஹ⌮+,᳛%Õ⊝ᔣ+,ᔣ3ÝC.╄ßxᑭᵨáᱨ□᩽Ḅ▢᩽äåᩭÔᑮ■èῖ⇨ḄéḄD.ᵯ±¹º»4□᩽ê
ëᨵZnஹFeஹAgஹAuìzT11ஹᐙᑖᑭᵨïᨵḄᦪð±ñᓄ´ò⚪Ḅô⌕⌶ö.ᦪðḄᑭᵨøùḄA.ᑭᵨᓄ´Õ⊝ᦪᑨûᓄ´+,üýḄþ᠒B.ᑭᵨᦪᑨᓄḄឋC.ᑭᵨᦪᔠᱥᑖ"ḄឋD.ᑭᵨᱥ#Ḅ᥅%#&ᑨ'()᝱+,(ᱥ#-Ḅᜧ/12ஹᵬஹ234CH3COOHḄpH,5ᵬ62ᜧ1,ᑣᵬஹ238A.c9ᵬ:;c92:=1:10B.cH+ᓫ;cH+2=1:2C.cOH:ᵬ;cOH:z,=10:lD.a9ᵬ:;a92:=2:113ஹ?@ABᐗDEFᓄ┶
CeOHM@4H⌕ḄFᓄᱥ஺KLᵯNOPQRST8URᜧ&ḄVWᴻYZ9[SiO2ஹFe2O3ஹCeO,\]⚪_`aYZbᧇdᦈfEghijkT᝞+;2

3+ᑡno,pqḄ@A.STজ8Ḅ@;Fe2O+6H+^=2Fe3++3HO32B.Sstu8ᵨᑮḄWᴻwᘤᨵz{ஹ|ᧅஹWᴻ~C.STঝ8ᨵ02ᡂD.STট8Ḅᣚ14ஹᑖᔣᙳb100mLஹᙳblmol/LḄNaClOஹNaOHஹClhCOONaḄ48ᐭCO2,ᔜ8n(HCO3-)Ḅᓄ᝞+ᡠP;(k0.020.040.060.0X0.10n{C0
1/mol+ᑡᑖ᪆pqḄ@A.CO2ᐭNaClOḄ;2ao+CO2+H2O=CO32+2HCK)B.CO2ᐭCHsCOONaḄ;CO2+H2O+CH3COO-HCO+CHCOOH33C.ᐭn(CO20.06molENaOH8Ḅ;2OIT+CO2=CO32-+H2OD.ᐭn(C02)=0.03molE48;n(HC03)+n(C032)+n(HC03)=0.03mol215ஹ2019b▭ᓄᐗDᕜ⊤஺&(Lv)@116ᐗD஺+ᑡno,pqḄ@()A.Lv£¤¥ᕜ¤VIAB.Lvᙠ(ᐗD8§ឋᨬ©C.LvḄ(£Dªᐹᨵ'(ḄᵯªᦪD.8ªᦪb177ḄLv᪶Db®Lv16ஹ®¯+E+ᑡᔜ_"ªᙠᢣ±8ᜧ&ᐳ³Ḅ@A.pH=lḄ8:NO\CI-ஹS2->Na+3

4B.c(H+)/c(OH-)=l()i2Ḅ8;H+,Al3+ஹNOTஹCl-N4C.ᵫ¶ᵯ"ḄC(H+)=1X10-I2moi•L-iḄ8;Na\K\Cl>HCO3D.c(Fe3+)=0.1mol•L-iḄ8;K+>ClSO2\SCN-417ஹ+ᑡᨵᐵijḄno8,pqḄ@()A.¸¹᪆o®`s¸ubºឋ»ᢝᱥEs¸½¾¿ḄÀÁᡠᔾ▬Ḅ¶ubı'B.ÅjÆÇᜮ8ḄÉᐗDEÊËÌḄÆÇᜮÍÎᙠÏ&¶8EᱏÑÒÓÏ&ÔÕ8EÖ×Ø⏚ÚÛAØ⏚C.ᙠ6Ü2⏣ÛÞßàáḄij8E⌕Ê2⏣ÛÞßâᡂ(ᱥ#Ḅ&Ḅ¶Eãà'(ᜧ/Ḅ§áEᩭᑨ3ὅÀÁ¿FḄæឋD.5çè,éêÍῖ⇨íîEᐜᵨÞðñEãᵨ¶òñ18ஹឋÚóᨵôEõ▾8®ᵨ÷⏚⚞ù4⚞ó(úû⚞⚶)ubᑁþ⌼ᑺ஺▾ᦗ⚞ὅ◀ᔢ᜜,◤⌕ᔣὅᐭ⏚஺!"Ksp(BaCO3)=5.1xl0-\Ksp(BaSO4)=Llxl()r஺஺#ᑡ%&'(Ḅ*A.BaCChḄ+,-ᦪ⊤012Ksp(BaCO3)=n(Ba2+)-n(CO2-)3B.4ᵨ2%5%ḄNa2s஺467ὅ8C.9:;?@⚞D.AᵨB⏚CD2ᑁ;⌼ᑺ=*G2Ksp(BaCO3)>Ksp(BaSO4)19ஹINA2JKLMN-ᦪḄO=#ᑡPQA'(Ḅ*A.᪗STU#=U.2LVWᵬY<ᨵᑖᦪ20.5NAB.-\-]#=2gD2O<ᨵᵯᦪ2NAC.46gNO2_N204`ᔠbc<ᨵdᦪ23NAD.ImoINaeᐰgO2hijᡂNazO_Na2(h,lmᵯᦪ2NA20ஹn\#=#ᑡᔜpᙠᢣstᜧvᐳxḄ*()A.().1mol-L-iNaOH"Na+>K\CO2\A1O<3B.{ᐭ|vCL:C}ஹSO42,Fe2\Al3+C.{ᐭᜧvCO2Ḅ"Na+ஹCIO,CHCOO>HCO33D.O.lmolLTH2sCh"K\NH\NO3ஹHSO3421ஹᱥᩖ(ᑁ2ᩖ)Ḅஹ◀ᩖḄᑺᡈQ'(Ḅ*⌱⚗ᱥᐸᩖ◀ᩖACb(HC1)ḄKI⛳_

5BNO(NO2)⁐ᡈḄKICCO2(HC1)AgNCh(<⏚)⛳_Na2cChDNaHCCh(Na2cCh)Ca(OH)2|vCO2D.D22ஹ-\#ᵨO.lmol/LNaOHs40mL0.1mol/LH2sCh=ᡠs᝞¢ᡠ£(¤ᶍ`ᔠc,Ḅ¦ᓄ)஺#ᑡ¨©┯:Ḅ*A.Ka2(H2sO3)Ḅᦪv«210-8B.9sᑮ®hi¯°=4ᵨᵬ±²Dᢣ£ᑺC.¢Y°³iḄ"3c(SO2-)=c(Na+)+c(H+)-c(OH-)3D.¢Z°³iḄ"c(Na*)>c(SO33)>c(HSO3Ac(OH-)´ஹµ⌱¶⚪(ᐳ84ᑖ)23ஹ(14ᑖ)¸#*ᨵ¹ᱥHḄᔠᡂº»஺00ᓄᑺHO0!"—D—H+—CH—K--------*ߟC^H-Oi—C—;^pCH.OHCHCOOH3HCHO/ᓄᡈ[0]CHQH/½⏚®,CgH஺஺?hiজ~C10H12O3C10Hl஺03ᓄᑺ/AA-CHOABCDEᑺa-------------G0H10O3-------->CHO4ᓄᑺ1---1-0--1-2--tÃÄÅ⁐hiঝa")஺FGH(1)জḄhiÇÈ*oঝḄhiᩩÊ*஺(2)ᑺa*.FḄË᪀Í1*.(3)hiঞḄᓄÐÑ1஺gEÒ2ÓᑖÔ᪀c=tÕÖ×ØÙÚᨵ®ÛÜݱḄË᪀Í1*(ᑏßᐸ®Û)(4)AᔠᡂE2à⌱¶áᩩº»ᩭᔠᡂ=ãA*A_HCHOäåᔠᡂ=ᳮᵫ*஺

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RCOOH50cb,RcociR0HRCOORXrফR-Cl-^3R-NH2HC1R-NH2HC1R^C0ClRCONHRrrr:"1
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ᑏ>?@ᔠᑡᩩBḄḄᡠᨵ>ᑖD᪀EজG᜜ᐝJ⊤Lᑖ=MNᨵOPQR8S73NaOHTU18212V789WX12;ঝH—NMRJZ[ᑖ=Mᨵ\]^>ᵬP`abcdᨵefᓄgb᛻Ḅi=஺"4
ᑏF~⏒ᵞ⏚Ḅᓄgjk&মᑭᵨ⚪pqrstuV
ᧇᑴᜓx=Ḅᔠᡂxᵨykz⊤[{|}ᑺ⌱____________________25ஹ"12ᑖQR᝞zḄkᑴ⏚xᜳᢝᘤ6ᘤᙳḕᶍ஺ᐸ12ᳮ
2NaS+NaCO3+4SO2=^=3Na2s2O3+CO222

7.70KH3O.1ᑡ'()*+Ḅ,—.A.AḄMḄ}ᑺ2,Na2sChEB.¡Cᜐ£¤Ḅ¥¦7§12¨᳛>?V7ªᜧᧇḄᑭᵨ᳛C.EḄ⌕¬ᵨ,ᔾᦈCO?¯°D.BḄ¬ᵨ±e,²³SthḄ9ᡂ¨᳛´ᜐ┵¶M·⌱ᵨ¸⏚ᡈ⛳6NaHSChTU212#»¼CMTUM½Nᨵ¾¿Na2s04ᩖÁÂÃᐸ9ᡂÄe஺26>10ᑖÅÆMNᨵeÇ¿Ḅ╅ஹÉÊᩖÁỚÆ·7NᨵK+ஹKb-ஹrஹMg2+.ỚÆMỚḄÌᜫ⌕,ᵫÏᩖÁஹ£ᑖஹаMḄ0°uÑᐝ᯿ஹÓÔÕḄ஺ÖIO3-+5×+6H+r3l2+3H2O,2Fe3++2r^2Fe2++IKI+I2-KI3
0ᓄឋIOy>Fe3+>12஺2>1g9ᵬÚÛỚÆÜÝ᝞QRu+Ç´ỚÆMỚᐗßḄàᙠ¶&஺eÇ¿ỚÆᵨ〉¿ãä£TÂ,æçÆ⏚⏚ᓄèᡠéTUᑖ
3ê஺ëeê}UMìKSCNTU¼ZG⁐îëïê}UMð¿KIETUZñò⁐ᐭCC14,ôTUZõG⁐îë\ê}UMᐭ〉¿KIO.,E¼ìö÷}ᑺTU)ø⁐஺জëeê}UMKSCNTUZG⁐´G⁐ᱥÁ,xᵨᓄg&⊤[஺ঝëïê}UM“ᐭCCL”ḄQRû¬üý
,CC14MZõG⁐ḄᱥÁ,xᵨᓄg&⊤[஺ঞ᪷
ᵬᙠỚ◀Na\CL᜜ᙠḄ,"#ᙠḄ,$ᙠḄ஺ᵫ&"'(ỚỚᐗ*+,-ᓄᔠ+0ḄỚ஺22L34KI35ᙠ67ᩩ9"ᑴKI.HO.(ᱥ<=>?Ớᑺᔲᔠ〉C,-“”ᡈ“ᔲ”0,32GHIᳮᵫ_____o3LMl2+2SO32->2r+S4O62-.NᵨPQRSTUVW?ᵨXᑴḄỚYZ,Ꮇ\$YFe3+,ᐸ^_>:2a.a'bcwg?〉Zdefgᐸhᐰ3jkb.ᵨlm⏚⏚ᓄᡠ35ᐭqZKI35gKIO3rKIRShᐰkc.st35>ᢣvᑺ⌲xᐭᱥ<ḄZyz>2.0x10-3moi/LḄNa2s2O33510.0mL,ា|RShᐰ஺᪷PNᡠWXᑴḄỚYZ,Iᐗ*~0mg/kg,YwḄᦪV⊤v0஺27ஹ12ᑖ0⏒NOC1⋎⁐5ᡈ⁐ᐸᰚ-64.5࠷,-5.5C,⍗f᧕fj஺ᨵᔠ

8ᡂḄ⌕ᑺ"ᵫNOrCLᙠ7ᔠᡂᐵ᝞¢ᡠv஺(DNOC1ᑖᔜ¤ᙳ¦q8ᵯ¨᪀ᑣNOC1ḄᵯV>(2)⌱ᵨXᑴᜓNO,Yᑴᜓ஺X®ឋḄᐹ±=:(3)ᑴᜓ⏒²®ឋ³ᐭ´µজ·¸◤ᐜᡭ·,¼____________²½ᡭ·ZᨵZ5ᡂ²¾¿஺ঝZÁḄRSTUV>஺(4)Â$ᵨAÃᨵÄÅÆ(ᵨᓄTUV⊤v)(5)ÉÊWNOC1᪵µḄÌz஺cZᡠ5l()()g34〉ZḄNaOH35Íᑴᡂ250mL35kc25.00mL᪵µ34┵ÏÐK2CrO435>ᢣvᑺᵨcmolLÑAgNCh᪗a35xÓÔÕὑ᪗a35Ḅ×>20.00mL஺xÔḄØÙ⏒(NOC1)Ḅ஺(LMAgzCrCh>Ẉ⁐ÛkK(AgCl)=1.56xlO10,Kp(AgCrO4)=1.0xl012K(AgNO2)=5.86x1O-4)spS2>sp28ஹ(14ᑖ)AINÜÝᩞᧇSᵨàáâãᐸᑴᜓrឋ<Ẇåᡂ>æ஺ᐵᦪ᝞ᱥ<ᰚ/C/࠷rN2RS7z/CSᓄᔠᱥᑖj7z/'CA1N>2000>1400ᓣê0AI6602467>800AlCh>181ᓣê0Mg6491090>300Mg3N2>800(DA1NḄᑴᜓ஺জᓄë×ì஺I.7zAlChíNH3>¤ᧇᑴᜓA1N,RSḄᓄTUVH.PQRS〉îḄ7zðr(-ñò)஺

9a.75~100b.600~1100c.2000-2300ঝ?@ABCᓄE஺AlFN2GABᓄᔠIA1NJKA1NLMAlᒹOPQRSTUVW஺XᑴZ[ᙠA1@=ᙳᒴ_ᐭ〉bMg@,GcA1deᐰghᓄIA1NJK஺ijklmḄPQᨵ8ஹq2A1+N2800-1400࠷2A1N.ঞstuvE஺SALO3ஹC(xy)qN2Ivᧇᙠ|Z}ᑴᜓA1N஺8i.2A1O3(S)=4Al(g)+3O2(g)AH1=+3351kJmol12ii.2C(xys)+02(g)=2CO(g)AH2=-221kJ-mol'1iii.2Al(g)+N(g)=2AlN(s)AH=-318kJ-mol123ᵨ⊝vᳮᑖ᪆PQiiPQiḄGL8஺(2)AINḄឋ஺A1N@Glm஺ᩩ}ḄA1N@pHḄᓄ᝞ᡠ஺PHlit,-♦-40nm—o—500nmজAIN@Ḅᓄ¡¢k£¤»ঝ¦§t2¨ᑁªᩩ«¬®ḄGLv¯8.(3)A1N°b±²஺ᔣagAlN᪵µ=¶ᐭ·b¸NaOHᯠº»ᐭ¼½MN%ᐰg¼¾MN%ᵨjbḄvimL2sO4ᔾᦈÁᐰᒕÃḄH2sO&ᵨv2mLe2moiNaOHាÅ=qᑣ᪵µ=A1NḄbᑖᦪ¤29ஹ(10ᑖ)ᵨ஺2MHC1hᓄICh,GÈ|ᦔÊËÌÍÎ,(1)ÏÐÑihᓄ»j᝞ᡠḄÒᓄᑺÔÕÖ×ᐸ=PQজI82HC1(g)+CuO(s)(g)+CuC12(g)AHiPQঝmᡂImolCL(g)ḄPQtIA¾ᑣÛPQḄtᓄ¡¢k£I(PQtᵨÜHiqܾ⊤)஺(2)ÞßRuthÒᓄᑺÑàHC1hᓄIChḄÛPQᐹᨵâÅḄÒᓄãឋজÖä²åᙠæçèé}ÛPQḄHC1⊝hᓄ᳛ëZ[ᓄḄauci—T«¬᝞ᑣÛPQḄAH—0(ì“>”ஹ

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ᳮᵫ______________oঞᑡᨵᑭaciḄᨵ.HAஹᜧn(HC1)Bஹᜧn(O)2CஹᵨḄᓄᑺDஹHO2(3)ᩩ"#$%&'(n(CI2)Ḅᦪ*᝞:t(min)02.04.06.08.0n(Ch)/10-3mol01.83.75.47.2-.2.06.0minᑁ0HC1Ḅᱥ2Ḅ34ᓄ⊤6Ḅ%&7᳛(0molmin-1:ᓫ<=ᑏ?-.'()஺(4)CLᵨ⌶CD=ᑏ?ᵨCbᑴᜓGHIḄᓄJK(L«óὃõᫀஹ⌱O⚪(ᐳᒹS22TU⚪஺VU⚪ᙳXᨵTYᔠ⚪[Ḅ⌱⚗)1ஹAூ᪆௃]^3SO2_ᐭCa(ClO”ab=cdeᓄfg%&=dᡂi⏚┛=ᵫCa(ClO)2'3=fdᡂHC1Ol=mn%&:SO2+HO+Ca2++2CIO=CaSO4
+HClO+H++CI,ᦑ⌱A.22ஹDூ᪆௃A.pqrstuᢝwxឤz

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B.bwḄxO2ᨵz⏚{|HCO\H+}ᡂCO2bwḄxO2oᨵᜧH+,ᦑ⌱B
3C.cwḄxO2xjᨵᓄ|Na+ஹCa2\NO\oᐳᦑ⌱C
3D.dwḄxO2yᨵ⏚FஹH+}ᡂ⏚HF,H+ஹNO\Fe?+}ᓄH}ᡂFe3+,Ag\C3}ᡂᓄoᜧᐳᦑ⌱D
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12᪀ᡂḄ|☢~ᑁ=D⚗஺⚪⌱C஺5ஹBூ᪆௃gᵯ□mnᔣ᩽=᪷*gᵯmnḄKᔣtA:᩽=᩽ᨵmn%&=ᵯ᩽%&L:cY^^OH+Ze-H+nOoH+Cr,B:᩽=ᵯ᩽%&L:CH3COO-8e+4H2O=2HCO3+9H+,*ᑖ᪆஺ூ௃A.gᵯ=ᵯ᩽ᔣ᩽=ᓽᵯKᔣA᩽UᔣB᩽=ᦑAzB.B᩽:ᵯḄ᩽=ᜫᵯn=cdeᓄ%&=ᵯ᩽%&L:CH3COO;8e-+4H2O=2HCO3-+9H+,B᩽¡¢□᩽,ᦑB┯¥zC.᪷*ᵯn¦ឤt=§᜜ᵯ©ᨵ0.2mole•«=_'2n¬ᣚ®ḄH+ḄTᦪ:0.2NA,ᦑCzD.A:᩽=$ᑮᵯn=cdfg%&=᩽ᨵmn%&=ᵯ᩽%&L:cY^OH+Ze+H+nO-OH+Cr,ᦑDzᫀ⌱B஺ூ²³௃᪷*mnḄKᔣᑨ¶gᵯḄ᩽¢⚪Ḅᐵ¸஺⚪Ḅ᧕┯²:B,⌕»[gᵯḄ¼᩽½:᩽=ᵯḄ¼᩽½:▢□᩽஺6ஹBூ᪆௃A.47.87¢ᐗÀḄÁÂᑖn23=ᦑA┯¥zB.ÃgnḄMÄÅᐳᨵ2+6+2=10Tᵯn=ᦑBzC.ᨬÇÈᐙ3dᵯn=:ÊËᐗÀ=ᦑC┯¥zD.22:gnḄgnÌᦪ=ᦑD┯¥zᦑᫀ:ÍB஺7ஹCூ᪆௃A.ÎᩰÐÑÒᡠᵨÔÕ¢ᔠÖ=×Ö×ᩞᧇ=ᦑAzB.Úᴻ¢ấ⏚Ýᩞᧇ=×ÞÎßÖ×ᩞᧇ=ᦑBzC.àá◞◫äå=ᡂᑖ:ᨵÎᑖnᩞᧇ=Ôæ¢Ö×ᩞᧇ=ᦑC┯¥zD.çᵨḄèéᑺ:êëÝ=ìÝabír7ÕḄd┤=&ï3ðUᵨ=ᦑDz

13ᦑᫀ:Co8ஹDூ᪆௃Aஹᵯm¡◤⌕_ᵯ=ᦑ┯¥zBஹᵯᓄJ■ῖ¡◤_ᵯ=ᦑ┯¥zCஹôᵯ¡◤⌕_ᵯ=ᦑ┯¥zDஹᵯ◤⌕_ᵯ=ᦑ஺ᫀ⌱I)஺9ஹBூ᪆௃ᙠᑖnö=ᓫ~«4:ᙠᓄJ÷ᡂÅøùúûḄᨬUᓫ<=ᓽö⁚=ᑨ¶ýᱥḄᓫ~=þ¢᪷*ᑖnö=ÿᔠᓫḄᳮᑖḄ⁚⁚4᪀ᐸᓫ"#$%&'()ᑖ*+#,-ᔠᓽ/ᓫ஺ூ23௃ᑖ᪆ᐸ⁚6⁚4᪀ᐸᓫ"#$ᓫ78ᢥ᝞;<=&஺ᵬ?ᓝ/ᓫ1,1-ABC7DᐰBF7஺,CFSᦑ⌱IB.10ஹCூ3᪆௃A.KLMᔣO.lmobLOḄP⏚RSTUVWc(H+)ஹc(C&COOH)ᙳYZ[VW\]^_P⏚ḄᵯaᡠcRSc(H+)/c(CH3COOH)eᜧA┯hiB.N2(g)+3H2(g)=^2NHWg)!!<()jk⊝(mnLopq᳛YZஹ⌮q᳛YZk⊝ᔣp<ᔣtuB┯hiC.╄wxyᙠ{|}~ᡂᵯw᩽ῖ⇨xp᩽ᑭᵨᱨ□᩽Ḅ▢᩽ᩭjᑮ■ῖ⇨ḄḄCpiD.ᵯ3□᩽▢᩽wஹxᡠcᜫᵯ¡a□᩽¢£ᨵAgஹAu¥¦§,D┯hi©ªᡠ«¬⚪⌱C஺11ஹCூ3᪆௃

14Aஹk⊝KᦪḄᜧZ¯°⌮_±Ḅ]oᜧZk⊝Kᦪ²ᜧᑣ⊤µᱥḄ·ᓄ᳛²¹°º»Loᦋ¡½ᦋ¡Ḅ¾ºᙠ⌮¿}¯i┯hiBஹÀᓄÁḄឋ◤⌕ᑨ&ᱥÆÀᓄឋÁឋḄÇÈÉÊ┯hiCஹËÌÍ*c⌱ᵨÎÏḄ<ᑖapiDஹ◤⌕ὃ⇋ᱥÆḄÒ᝱|DSÔᨵឋ┯h஺12ஹCூ3᪆௃A.ᵬஹC#$CH3co0HRSḄpH,×ᵬCᜧ1,ᑣØoCᵬḄ10ÙÁ⌕ᜧA┯hiB.᪷ÛÜaØo¥Ý10-PH6c(H+)ᵬIc(H+)C=110,B┯hiC.⏚RSḄÜÀ᪷Øo¥ÝUᵯaḄÜÀ᪷aØoc(OH-)ᵬIc(OH-%=ÞI,^=101,C'ஹ/C1Q-pHT1Q-pHZLpiD.᪷Ûª«ᑖ᪆ãa(ᵬ)a(C)æ¥Ý21,D┯h஺çᫀ⌱C஺13ஹDூ3᪆௃ê\]IজCeChஹSiO>FezCh¥TᐭVì⏚FezCh·ᓄFeCbíᙠÝîSAîïACethDSiCh;2ঝTᐭVñ⏚DH2O2,Ce(h·ᓄCe3+,îïBSiCh;ঞTᐭó(Ce3+·ᓄôõট÷ᐭÀ|+Ce%+3øÀᓄ+4ø/ᑮùú஺᪷Ûª«ᑖ᪆6\]জFe2(hüì⏚⌱⚗Apiᔠ\îþÿ⌕
ᵨᑮḄᴻᘤᨵஹᧅஹᴻ⌱⚗B⏚ஹH2O2ஹCeChὅᡂCe2(SO4)3ஹO2"H2O,Ḅ#$%&'(6H++H2O+2CeO2^=2Ce3++O2T+4H2O,⌱⚗CD)Ḅ*24Ce(OH)+O2+2H2O^=4Ce(OH)4,+,ᓄᔠ⌱⚗D┯0஺314ஹDூ5᪆௃A.89⏚Ḅ⏚ឋᜧ,<⏚=᪷#$ᡠ@ᡂ89⏚"<⏚=᪷#$ᑣBCDEᓄ2)=0.03moI,RHISᙠ<ᐗVḄᱥᧇXឤZᑮJn(HC03)+n(C032)+n(H2C03)=0.03molI,D

15ᦑᔠᳮ⌱⚗*D஺15>Bூ᪆௃ᵫ_`abcde118fᐗVb,ᐗVᕜh⊤jkᕜh_`ᑣ116fḄ^(Lv)b,ᐗVᕜh⊤jkᕜhjVIA`஺ூ௃A.ᵫ@mᑖ᪆deLvb,ᐗVᕜh⊤jkᕜhjVIA`ᦑAB.op`ᐗVᵫmqrs+ឋ⌲uvwᑣLvᙠop`ᐗVs+ឋᨬwᦑB┯0C.obVy$z$ᦪஹᵯ$ᦪ}o$ᦪNoᦑCD.$ᦪ(177ḄLv᪶VzCᦪ=116+177=293,ᑣ᪶Vf(Lv,ᦑDᫀ⌱B஺16ஹBூ᪆௃A.pH=lḄHIᕈ⏚ឋH\NO3,S2-)EᓄyNᜧCᐳS⌱⚗A┯0B.c(H+)/c(OH-)=l(p2ḄHIᕈ⏚ឋH+ஹNH\Al3\NO\CE}NᜧCᐳS⌱⚗B43C.ᵫᵯ#Ḅc(H+)=lxl()T2mo1.LTḄHId(w⏚ឋd(wឋHCQ,ᙳNᜧCSᙠ⌱⚗C┯0D.c(FeJ+)=0.1mol-L-'ḄHIJFe?+SCN)ᔠNᜧCᐳS⌱⚗D┯0ᫀ⌱B஺17ஹCூ᪆௃A.,H,Ḅᑖ#ᱥzmḄᡠᔾ▬Ḅ(a}@¡ᔠḄᨵ¢Hᑺ¤¥}ᦑAB.¦9#$Ḅ%c*ᔣHI¨ᐭ©⏚ª"©⏚ᨵ«⁐®ᡂ¯°ᨵ9#$SᙠᦑBC±²³⏣"µ¶·ᡂoᱥzḄC¸¹ḄHIᑣQᐜ"»ᦑC┯0D.µ*ᨵ¢Hᑺd@¼½H5¾¿ᓻÁÂᑮᨬÃᡠ@±ÄÅNÆÇÈῖ⇨ËÌᐜᵨµÍÎÏᵨÐÎᦑDÑmᡠÒᫀ(C஺18ஹBூ᪆௃ÓÔ⏚dC03z-ᡂ"DEᓄ<¿CO3?-¸¹ÂÃÕ¿Ö⊝BaCO3(s)WBa2+(aq)+C(h2-(aq)ᔣH5%ᔣØ¥ᑣBaCChH,Ô⏚⏚QNH,⏚ÙᔠH¹Ú5Û⚪஺

16ூ
௃A.xÄÅᦪP)ÇÈÄBaCChḄxÄÅᦪ⊤ÊKsp(BaCO3)=c(Ba2+)-c(CO32-),ᦑA┯W$B.᪷Ë;,2%5%ḄNa2s04xO2Na2sChḄᱥjḄ)0.13mol/L0.33mol/L,ᵨM11in-1011xin-10x0.13moVL~0.33mol/LḄNa2s0ÌxOÍÎP2ÏÐὅÒÓ.c(Ba?+)=-----------mol/L------------mol/L,0.130.33)ÔÕÖᑮpÏḄCᵨᦑB"#$C.c(Ba2+)=1.0xl0-5molLTḄxO⚞P)ÔÕÙÚÖ⚞P2ÏᦑC┯W$D./Ó⏚
C(h2-}ᡂᓄzCO32-)ÜÝÞßà⊝BaCO3(s)=Ba2+(aq)+CO32-(aq)ᔣxpdᔣâãBa”)äᜧBa?+ᨵÏ
&pᜧÕåᐵᦑD┯W$ᦑqᫀ⌱B஺ூ௃tuæxO2çP)e<1.0x10-molLT'èéPᙠÙ⌼ᡂb▭íî஺19ஹAூ᪆௃A.᪗ðñòóôᵬO᝱åöᵫÄ÷øᑖᦪᦑA┯W$B.D2OḄ᥅új20g/mol,2gD2஺O.lmol,ºᑖ2yᨵ10ᵯᑣyᨵᵯᦪNA,ᦑB"#$46g.³C.NO2N2O4ḄᨬüÁ°ᑣ%ᔠ2yᨵHᦪý
x3=3mol,ᓽ3NA,ᦑC"#$46g/molD.ImoINa}ᡂNazONazCh,|Hᜫ1
ᵯᡠᵯᦪImol,ᓽNA,ᦑD஺ᦑ⌱Ao20ஹAூ᪆௃A.O.lmoFLTNaOHឋᐳᦑA!B."ᐭ$%CLḄ⏚ឋ()ᓄឋFe2+ᨵ-.ឋ/)ᓄFe3+,0ᐳᦑB┯2!C."ᐭᜧ%CO2Ḅ⏚ឋH+4CKTஹCHCOO\HCO3-0ᐳᦑC┯2!3D.O.lmollTH2s04⏚ឋH+ᙠḄ789Nth-(HSO3”)ᓄ-.0ᐳᦑD┯2஺:ᫀ⌱A஺21ஹBூ᪆௃A.<=Ḅ>?KI@AB0CDEF0CDHC1,CDHC1ᐜᑖICDA⚗┯2!B.NCh0)ᓄỚᓄLNth4MᡂNO(O⏚ᵨM◀ᩖB⚗!

17C.CO2(HC1T4⛳(V⏚Wᵨ⛳(V⏚XWC⚗┯2!D.NaHCCh(Na2cChT4Ca(OH)2ᡂY>0ᵨᩭCDD⚗┯2;:ᫀ⌱B஺22ஹDூ5᪆௃c(SO2jc(H&)3A.\]^C(SO32-)=C(HSO3")B^pH=7.19,Q(H2so3)=e(H+)=10-7J9,ᑣKa2(H2sCh)Ḅᦪ%`108,c(HS0)ᦑA;B.ᵬbcḄd⁐g3.144,hijklmpHᙠ4.25,ᡠ⌱nᵬbcoᢣqᑺᵫt⁐dc⁐,ᦑB!C.Ymvᙠᵯ₹xឤc(Na+)+c(H+)=2c(SC>32-)+c(HSO3-)+c(OH-),z{maSCVA&HSCh-),ᡠᙠ3c(SO32-)=c(Na+)+c(H+)-c(OH),ᦑC!D.Zm|Na2sCh,SCV-M}ᡂHSO-S(V-M}(MᵯTᡂOH1ᡠC(HSO3-)VC(OIT),ᦑD┯2;ᦑ:ᫀD»ூm௃H2s஺3ᐗ⏚4X)ᓄWᐜH2sO3+NaOH=NaHSO3+H2஺INaHS€)3+NaOH=Na2sO3+H2O,ᡠjklm|NaHSCh,ᕈ⏚ឋ⏚X᪷ḄᵯᜧM}!jlm|NaSO«23ஹ⌱⚪(ᐳ84ᑖ)Þß-CH20H23ஹᡂ⏚ஹCHjCOOHCHCHCOOH2OHCHOHk⏚CH2OஹCJ-CHQOCH2/=o+HO■ᵬ⏣ḄCH=CHCOOH2CH=CHᵬ⏣(⏚ᙠ⏚ᓄ9ᓄᡂB([:CHQOCC%),B(ᵬᡂC,Cᓄ)ᓄᡂD,

18DI(NaOHᡂE¡"OH,᪷\EḄ¢᪀¤¥¦§^D-E¨ḄM}ᡠD|j^j-CHOOCCHj,D¨Cᓄ)ᓄᡂḄᡠC©ª«fgCCHᑣB(ᵬḄ¨ᡂ஺E-F¬:OᔆCH20H2
V.(2
).᪷\®¯Ḅ°^§±@ᑺaCH3COOH,ᡂḄFCHCHCOOH
2OHᡂG¡0²³M´⁐µGᑖvᨵVV¶·F¸ᡂḄ¢ᔠHḄ¢᪀¤¥^Gr^r-CHzOHCH=CHCOOHூº}௃OᔆCH20H1জ¨O-SiOOCCH,(ᵬᡂ
QtM¼CC”,½¾¨ᡂ!ঝ¨1tCHCH28OHḄxOH⏣b¸ᡂCÁCCHḄᡠ◤@ᑺ¨⏚ᩩŨ;Þஹ820H2ᵫEᡂF᪷\ᑖ¥Ḅdᓄ§¯aḄ¢᪀¤¥¨CHCOOH,FḄ¢᪀¤¥¨L^LHCHCOOH?3C2OH3ঞ¨Cª«ÇÈ””ḄᑖᑁᓄᓄËÌ¥:CHOÎÏCH20Hk⏚2X^C=O+HOCH=CHCOOH-2CH=CHECcᱏ,4EÑÒᑖÓ᪀Ô0M}ᓽ◤⌕ᨵbzÖ×BᨵkØnÙbÒᑖÓ᪀ÔCH2OOCHOOCCHᡈ34ᵬ⏚Ḅ⏣bÛ᧕ᙠ$v/)ᓄAᔠᡂE⌱⚪vÝÞᩭᔠᡂ.ߨ■ᵬ⏣Ḅb/)ᓄ;5⌕ᔠᡂ4k஺à×,◤⌕ᨵᓫÔ஺-CH=CHᵫ©"cH,cmᑴãOr1cH3ᡈopenä,

1924ஹ000HI4CH30HoᵨãᑮḄDR000cH'!JU/4SOCLoᵨᡂḄC4SOC12oᵨᡂḄECl,E4DoᵨᡂḄFHCHjCOOCHs,FIᙠNaOHvM}ãçèé⏒ᵞì⏚W(1)ᑏ¯ᓄᔠᱥḄ¢᪀¤¥ïBH2NCH2coOH
D(2)A.<[HiCKjOHᓄ)ᓄᓄCICH2COOH,½¾)ᓄᦑA!B.RCOOH4SOCLnaÙᡠãöᱥRCOOClஹSO2(HCLᦑB!C.ᓄᔠᱥBìb⏚kiᩩÅ90÷øᦑB!D.çèé⏒ᵞì⏚WḄᑖ¥GsHzoNChNa,ᦑD┯2!:ᫀD஺(3)জt᜜ᐝû⊤ᑖvýᨵ⏋bÿ
NaOH12
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ঝH-NMRᑖᨵᵬ"#$%ᵬ"&'ᨵ#(ᓄ*᛻Ḅ-%./0'ᨵ12ᨵ3/Ḅ45"0678192:Ḅ-%᛻;<ᩩ>Ḅ(4)F-?@A⏒ᵞD⏚FḄᓄ*GHIJHCHjCOOCHa.OOmOhOOONi.CH/M.

20(5)6?11cH20HJ%ᧇᑴᜓU)ḄᔠᡂYZJF3coNH»fHcoOHSOCUfH[3C,&NHjNHj-HCI\]^_⚪⚪abcdefḄgh*◤⌕k⚪lbghmᨵnopqrstuᔠvᵨxyz_⚪Ḅᐵ|◤⌕*ᐹᜓ~ஹ4ghḄஹᔾᦈஹ᦮ᔠᓄ*ghḄᵨ⌮ᔠḄG⌲ᑖ᪆ᨵᔠᡂYZ0cᔜᨵᱥḄ᪀Iᯠᑖ᪆ᔜ&¡\xᨵᱥDḄ᪀¢0ᐜ᪷¥FḄ¦ឋ¨yᔠ©ᱥ¢cF,ªᑭᵨDEᡂF,0¬$®᪀ஹ%ᳮ%°ឤᑖ᪆²DḄ᪀஺25ஹBCSChNa2cChᡂNa2sCh,Na2sO3/´¢µ᧕·¸¹ºᓄᡂNa2so4,»ᡂḄNa2s2O3᧕·¸¹ºᓄᡂ¼⏚Fூy᪆௃A¿:ᑴ4Àºᓄ¼
ḄÁGHIJSO32-+2H+=SOH+H2O,B¿:ÂÃÀºᓄ¼»ÄÅᐰÇḄÈᵨAÉ᪷¥¹ÊᜧÌÍᑴ᳛C¿:
2Na?S+Na2co3+4S(h=3Na2s2O3+CO2,ᒕÐḄÀºᓄ¼ᨵÑ/᣸¸ᡠ6EJÔ¹ᜐᳮ¿:ᔠ⚪lᑖ᪆yz஺ூÖy௃(1)A.¿:AḄ×ÇḄØᑺxNazSChÚÛᑖÜᧅÞßḄÛx¼⏚ÀὅᙠA
ᡂÀºᓄ¼,ᦑA&B.äåCᜐ¨æçèḄéêç᳛ëx¹Ûìíᜧîï%ᧇᑭᵨ᳛ðñᦑB┯ó&C.¿:EḄô⌕ÈᵨxᔾᦈSO2Ô¹■öÀºᓄ¼÷ø᛻ᦑC┯ó&D.¿:BḄÈᵨù#xúûSO2Ḅᡂ᳛üᜐ┵þÇ0⌱ᵨ
⏚ᡈ⛳NaHSChὅᡈᓄᡠ⌱
⏚ᡈ⛳⏚ᦑDᦑᫀ"#BC
(2)$%&C''()ᨵ+,Na2s04ᩖ.SChNa2c03/ᡂNa2so3,Na2sO3123᧕567ᓄ/ᡂNa2sCh,8/ᡂḄNa2s2O3:᧕567ᓄ/ᡂ⏚ᡠ;ᑮḄᱥ.')ᨵ+,Na2sCh,ᦑᫀ"#SChNa2cCh/ᡂNa2sCh,Na2sO3123᧕567ᓄ/ᡂNa2so4,8/ᡂḄNa2s2O3:᧕567ᓄ/ᡂ⏚஺26ஹFe(SCN)3⃓L10Fe3+Mg2\K+I+5ᔲKLCD(ᡈFG)ᩩJKL/KIaKI57ᓄL᧕ᓣN3wூ᪆௃

21(1)জÕjáâIã¨KSCNHIäåæ⁐deÛ¨ỚèéᨵFe3+,JFe3++3SCN-=Fe(SCN),Fe(SCN)33ᕈ⊈æ⁐ঝÕjDáâI¨ìCKIíHIåîï⁐ᵨCCL⃓ñròHIåóæ⁐deᨵỚᡂ஺ঞõ*Ó(ᵫ,EᓄឋJI0
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(2)KIy#ỚᑺḄzᙠ{9|}KI~ᓄ᪷-⚪KUH2Oqᙠ2ᩩ3ᵫLKIᑴfᵫ⚪ḄM“KI+Lh”KLᙠ12345ឋ(ᡈ)ᩩ3᧕ᑖ?#KIih,KI᧕ḄᓄL᧕ᓣᡠ:KNH2Oy#zỚᑺqᔠ〉ḄᦑVᫀ#Mᔲ+KL(ᡈ)ᩩ3(KIiKIᓄL᧕ᓣ+(3)᪷-)*ᡠ¡¢ᑴḄỚ(:Iᐗp;)qxmg/kg,ᑣKIO~3I,~6NaSO3223127000mg6molwxO.OOlkgxxmg/kg2.0Lx103mol/Lx0.01Lh¥⊟§ಘtgḄQH•©127000x2.0xW3x0.011270ªᡠ¡¢ᑴḄỚqx=------------------------------------=—P
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221270ᦑᫀ":3w27ஹMoMMsMiMST7UVWXYUZᵨ[\ᜳ^_ᔣUaUbU^\cbU☢efVU☟[ᱏij☢klᑣ7nឋpqrஹK3A'ᐙᨵtu⁐7wxKx2NO+C12=2NOC1NOC1+H2O=HNO2+HCIyᐭᨬ&|y᪗~/ᡂẈ⁐8ᑖᑁlᓄ13.1c%ூ᪆௃(l)NOClḄ'"N,ONᐳᵨᵯC1Nᐳᵨ|ᵯᑣᵯ",ᦑᫀ":•••••MoMMxM1M+ফᑭᵨᜧ7XḄ7nឋᦑᫀ"#ST7UVWXYUZᵨ[\ᜳ^_ᔣUaUbU^\cbU☢efVU☟[ᱏij☢klᑣ7nឋpq(3)জᐜᡭ¢2ஹK3,£ᐭ|¤x¥C12,᣸§ᑁḄ67¨ᡭK,£ᐭNO©ᨵ|2,ḄNOC1L/xª[ᦑᫀ"#«ஹKA'ᐙᨵtu⁐7wxK+3iঝZ"NOCLᙠ®KᔠᡂNOCL°±"#2NO+C12=2NOC1,ᦑᫀ"#2NO+C12=2NOCI+(4)AḄ²ᵨ³■[67'Ḅ7\µ7¶ᐭZ஺·ᨵA67'Ḅ\µ7¶ᐭZ,¸⏒º⍗\᧕¼/\#NOC1+H2O=HNO2+HC1,L᳛¾¿ᦑᫀ"#NOC1+HO=HNO2+HC1+2(5)K2Cr()4"ᢣÁᑺᵨAgNCh᪗~y2y2ÃÄxᵫÆ⁐l"Ẉ⁐ᑖᑁl⁐Çxn(Ag+)=n(C1)Z'ᡠ;100gf〉,ḄNaOH'Éᑴᡂ250mLr25.00mL᪵Ìf┵ÎÏ'25mL᪵Ì'#n(NOCl)=n(Ag+)=cmol/Lx20.00xl0-3L=0.02cmol,Ð!]250mL'n(NOCl)=0.2cmol,13lc2m(NOCl)=0.2cmolX65.5g/mol=13.1cg,¸⏒º(NOCI)Ḅ.,ᑖᦪ"|Ôcx100%=13.1c%,ᦑᫀ"#yᐭᨬ100g&|y᪗~/ᡂẈ⁐8ᑖᑁlᓄ13.1c%஺ூÄÕ௃Ö⚪ØÙὃÛᱥ.ᑴᜓ°ᫀḄÝÞ"e⚣ὃÄà⚪aá⌕ὃÛ°±ḄãᑏåæḄÝÞᓄçÞèéç/Ḅᑖ᪆ê⚪ëê⚪Ḅìíᨵîe⌕ï஺28>A1C1+NH3=A1N+3HCIb3Mg+N38

23(1)জI.A1CL,iNHᑴᜓA1Nqᓄ%&)*᪷-ᐗpÚឤÜÝᓽ+n.᪷-⊤ᦪ-ᑨâ+ঝ᪷-⊤ᦪ-ᜧ300C,╅iå)*ᜧ800࠷åᓄ╅~ᑖ?+ঞ)*iiCçὑ)*i(ᡂ+(2)জåᓄéG?(êᓄéiPGᔠë+ঝ)*ì᳛iîï☢ñᨵᐵ+(3)✌ᐜ;<çὑõ⏚Ḅᱥ÷Ḅëiõ⏚ᢥ᯿2:1)*fgëḄᱥ÷Ḅ᪷-åᐗpÚឤfᑮåᓄéḄᱥ÷Ḅᯠ;<÷ᑖᦪ஺ூ>?௃(1)জI.AICI,iNH,ᑴᜓA1N,)*Ḅᓄýþ}qA1CL+NHÿA1N+3HC1,ᫀA1C1+NH=A1N+3HC133n.᪷⊤ᦪ⌕AlCh◤⌕ᜧ"181࠷,᣸◀a,AINᜧ"2000࠷+ᑖ-᣸◀c,ᦑᫀ⌱bঝ᪷⊤ᦪᜧ"300࠷,╅4567ᜧ"800࠷5ᓄ╅+ᑖ-300-800࠷>800࠷ᦑᫀ3Mg+NMgNMgN3Mg+N232322ঞ67ii?@ὑB67iCᡂBᦑ67ii?EF67iGᔣFIᫀ67ii?JKBLᨵᑭ"67iGᔣOP(2)জ5ᓄTU-VCWBᓄT4XUᔠZᦑᫀAIN+4HO=Al(OH)+NH.HO2332ঝᵫ^_`abcdᩩfgḄ67i᳛klmḄ67i᳛4no☢qᨵᐵᦑᫀstuvḄA1N⊤☢qᜧU-67i᳛uᜧ(3)@ὑw⏚ḄᱥzḄ{|jxlO-mol,Z4w⏚ᢥ᯿2:167,ᦑZḄᱥzḄ{2x[c]V[xlO^mol,᪷5ᐗឤ5ᓄTḄᱥzḄ{k2*£^xl0-3mol,ᦑ᪵5ᓄTḄz{ᑖᦪ2x("V2~b1°=41Ji,-----------------------------x100%=-------_------aa

2441X(2CV-CV)10''ᦑᫀ":I122a29ஹ2HCI(g)+1/202(g)^=^HO(g)+Ch(g)H=AHi+AHaHa?@ABᓣ>;<C⊝ᔣ⌮ᔣFGᑣ(8⌮+,ᔾ.+,ᡠI+,%J.+,ᦑAHV0,LᵫNᓣ>;<C⊝⌮Fᑣ&ᡂᱥ?O;<%BPᜧNAPᡠC⊝QᦪK(A)>K(B)
ঝLᵫNS6+,%TUVᦪ?@Ḅ+,ᡠWXUYZW[\ᜧ]^;<_C⊝,IᔣFG39,b⚪de᝱_ᜧᡠ(ghঞAஹ\ᜧn(HCI),C⊝IᔣFGi%C⊝FGZHC1?OḄjk@N\lHC1Z\ᜧḄjkᡠHC1Ḅᓄ᳛?@┯7Bஹ\ᜧn(O),+,ᱥḄo<\ᜧC⊝ᔣIᔣFGHC1ᓄ᳛\ᜧp72

25CஹZᵨrsḄtᓄᑺvwZᓄ/C⊝x&FGHC1Ḅᓄ᳛vy┯7DஹFzH2O,{?@|&ᡂᱥḄo<C⊝ᔣI+,0ᔣFGHC1ᓄ᳛\ᜧ஺ᦑ~ᫀ%⌱⚗BஹDo(3)⚪d*Ḅ%n(CI2)Ḅᦪ⌕Ḅ%HC1ḄᱥḄyᓄ⊤Ḅ+,᳛ᡠ᪷012,%2.06.0minᑁḄ᳛ᓫ%mokmin"2.06.0minᑁHC1ᓄḄᱥḄn,J2HC1(g)+1/202(g)=HO(g)+C1(g)2221n(5.4-1.8)xl0-3moln=7.2xl0-'mol,ᡠv(HC1)=7.2xl0'3mol/(6.0-2.0)min==l.8x10'3mol/min(4)CLᮞx&+,ᑴ+,Ḅᓄ/0122Ch+2Ca(OH)2=CaCh+Ca(CIO)z+ZHzOo