浙江省慈溪市六校2021-2022学年高三二诊模拟考试化学试卷含解析

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9(2)ÑÒÓ8BC2ÔḄ&'pHÕÖ801Ḅ%×஺(3)᪷ÙBC2ஹ3ḄBCTÚ8ᵬÜrBC3&'_ÝᵫÞFe?+à(SCN”Yᓄ8ᑏ±&'_ÝḄ7#].áâ9BC2Ḅã'>5äᜐᳮ8Cç@è5déḄ01ឋ஺ᓄ&ឋ]¡JC4Ὦ2Ḅ£⊡ᐙBC4Ḅ)Ḅ᣸◀@&'îᙠCM+Ḅ018ïḄTÚ(4)ðñ8᪷ÙYᓄò%%ᳮ8ᙠóᩩ¬8CM+ô1YᓄFe2+,õḄᑨr÷Ù(5)᣸◀ø᡾8ÖËMúûb᝞ÌÍ஺জA&'஺ঝ“ᵯþ⊤ᢣ┐CuFe"”ᔲᔠᳮ(ᔠᳮᡈᔠᳮ)O_ঞ"#Fe3+ᔲ%Ḅ'(o27ஹ(12ᑖ)+,-⏚/ᙠ12ᩩ456ᑖ7ᡂ9ᓄ/ஹ;9ᓄ-ஹ<9ᓄ-=9>஺@ABCᵨ᝞CᡠGHIᩭKLMᓄANᔜᱥQḄRSᐵU஺BVW:

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11
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4ᑡᨵᐵᓄᔠᱥCஹDḄ§¨]©Ḅl.জ7ᵨ¬ᓄ®¯␺±CDঝCஹDᨵḄ8²ᐰ´QঞCஹDµQᑖ᪀tটCஹDᙳ8¶·¸¹⁐5EḄQᑖ᪀t»¼ᑏ½ᔠᑡᩩḄ¾✏ÀQᑖ᪀tḄÁ᪀Âx»জÄḄ¬=ᱥÅᨵÆঝᨵÇঞ8ÈÉ%ὃWᫀஹ⌱Ë⚪ᐳᒹÎ22H⚪஺ÏH⚪ᙳÅᨵ½ᔠ⚪ÐḄ⌱⚗1ஹDூ᪆௃A.1ḄÒÓlᢣ1ᵫÖ×᝱d!ᓄᔠ᝱N—>NH31ḄÒÓÙNH3—>NObÚÛ1ḄÒÓA┯Ý42B.EᓄᑺaÞᵨ1TßTB┯Ý4C.Eᓄᑺaஹb⊤☢ᙳß᩽ឋᐳäåḄæçOèᡂC┯Ý4D.¶ᵨEᓄᑺaஹb7Dé,᳛êAᓫì0sᑁᡂᱥḄ3D]©஺ᦑ⌱D஺2ஹAூ᪆௃îÀᐗðWஹXஹYஹZḄTñᦪòóRDᙳbᜧÛ20,WOZèᡂḄ×ᓄᔠᱥ7O¸ᐸᡂḄ2t7¶⏚ឋAö⏚÷®¯¹⁐ᑣ2tùúᡈᙽüWCஹZCa0ᡂýé½ᔠ4WஹXஹZᨬ᜜ᵯᦪ

129,XḄᨬ᜜ᵯᦪ9-4-2=3,XAl
WYᔠᦪYSi,ᩭ஺ூ௃ᵫᑖ᪆WCஹXAlஹYSiஹZCa஺A.$ᱥᑖ&'()᪀ᡂḄᑖA,-.B.XḄ/ᓄᱥ/ᓄ123ᵨ56789B┯;.C.<=⌱?⏚┛ᵨ5BCῖC┯;.D.SiᓫFGHIḄJKLᩞᧇD┯;.ᦑᔠᳮ⌱⚗GA஺ூBR௃S⚪ὃV᪀ᐗXᕜZ[Ḅ\]^ᦪஹᐗXḄ_`a&ᓄ┛bcd$ᡂefᩭghᐗXḄᐵjklᐗXᓄᔠᱥ\Ḅdᵨmnᑖ᪆dᵨ3oḄὃV஺3ஹAூ᪆௃AcpḄNaOHqrḄsᵨGᔾᦈvcdḄCL,23ᵨNaClqrᦑA┯;.B.eGwxsᵨdyz{|{}ᦑB,-.CSO2cL⍗b᧕bᡠd■b|ᐭᦑC,-.Dbᨵsᵨ᪷⚪SO2c12᧕rᓄ3SO2C12Ḅᓄ᳛ᦑD,-.ᦑ⌱A.4ஹCூ᪆௃A.FRP5ᔠᩞᧇ25ᩞᧇA⚗┯;.B.ETFEᑁ5e¡-£¤e¡ᐳ¦ᱥ25ᩞᧇB⚗┯;.C.§¨¨Ẉ5ᩞᧇC⚗,-.D.ª«¬ᑁᨵ<ᓫᔣ¯ᔾᦔdḄᓄᩞᧇ᜜G±ᑴ³25ᩞᧇD⚗┯;.ᫀ⌱C஺5ஹCூ᪆௃জ⁐qrp2·ᨵᕈ¹⁐ḄMnOf,জ2ᔠ⚪l.ঝCO3*,AIO2-º3»$bcd¼qrᕈ½ឋঝÀᔠ⚪l.ঞÂᐭA13Ã}H2Ḅqr3ᕈ⏚ឋÄ3ᕈ½ឋÅHCO3•º23ᜧÈÉᙠঞ2ᔠ⚪l.টÂᐭMg3Ã}H2Ḅqrᕈ⏚ឋNH\Cl\K+ஹS(V-º3ᜧÈÉᙠটÀᔠ⚪l.4

13ঠ\]^_`Ḅabᕈ⏚ឋFe3\MnO\N0\Na\SC^-f6ᜧShᙠঠiᔠ⚪kl43ড⏚ឋabNFe2+ஹNCh-ஹrn9ᓄo6ᜧShᙠডᔠ⚪k஺pᔠqrᑖ᪆tᨵঝটঠiᔠ⚪k஺ᦑ⌱C஺6ஹBூ7᪆௃A.|⏚}9ᓄ~lB.⏚/ᡂ;9ᓄ>lC.,NᐭSO2>9ᓄolD.}9ᓄ/aaa஺ூ7௃A.}9ᓄ~6a|⏚ᵫ>HCLᦑA┯lB.5Cu-⏚ᡂḄ`⁐>;9ᓄabN6ᨵNOV,⏚Cuᙠ56ᡂ9ᓄ9ᓄ⍗ᑮ9>_`⁐;9ᓄ>ᦑBKlC.,NᐭSO2>ab¡⁐9ᓄoᡂ-⏚=HBr,;9ᓄ-ḄoឋᦑC┯lD.ᐜ£¤⁐¥¦}9ᓄ/a§¨|Ksp[Mg(OH)2]>Ksp[Cu(OH)2],ᦑD┯lWᫀ⌱B஺ூª«௃¬⚪ὃ®"¯ᫀḄ°±²³ᐗµᓄᔠᱥឋQஹaᜧ¶·ஹ¸Ḅ,7¹ºB⚪»¼½A¾ẠºḄÀÁ=Â"ᨵᑭÄÅAḄÆÇÈᳮ6ÉÊËAᮣÍÎᵨ¾Ạº7Ï®▭Ñ⚪Ḅ6É஺7ஹDூ7᪆௃HINrÒḄPtᵯ᩽᜜ᵯÖ×᩽ØÙ(▢᩽l5ÛḄCdᵯ᩽᜜ᵯÖḄ᩽ØÙ(□᩽l⚪Nᢣ£CdḄÝÞÍßឋᜧCu,ᡠq□᩽CdḄ9ᓄ▢᩽ᑣH+Ḅol᝞áâᵯÖḄ×᩽ãᑣPtᵯ᩽□᩽crḄᙠPtᵯ᩽ᜐå9ᓄᡂCL,Cdᵯ᩽▢᩽Ḅo஺ூ7௃A.ᵯPt▢᩽Cd□᩽ᡠqH+=Cd2+ᔣPtᵯ᩽çècrᔣCdᵯ᩽çèA⚗KlB.ᵯPt▢᩽Cd□᩽ᑖêH+Ḅo=CdḄ9ᓄᡠqë¯ìíîᵯCd+2HCl==CdCl+HB⚗Kl22C.ᵫïMð☢ḄëᵯS5.0C,ᐸNH+çèḄᵯS4.1C,ᡠqC1-çèḄᵯS0.9C,ᡠqHC1abNH+çèó᳛õC1-Ḅ4.6öC⚗KlD.×᩽÷ãᑣrÛḄPtᵯ᩽□᩽C1-ᙠPtᵯ᩽ᜐ9ᓄᡂC12,D⚗┯l

14Wᫀ⌱D஺8ஹAூ7᪆௃Aஹø=ùᓄøᡂᱥùᓄúøAKlBஹNaOHûᔾᦈCO2,ᡠqK⌱ᵨ⛳=Ḅ|⏚}ÿ
BCஹᓄ⌱ᵨḄCDஹᐭ〉NaOH
ᐭᓄ!Dᦑ⌱A,ூ$%௃◀ᩖḄ⌕*+,஺ᓽᐭ/ᩖ0,12⌕ᡂᑖ᝞B⌱⚗NaOH7CO22⌕ᱥ09ᦑ┯;஺9ஹDூ<᪆௃Aஹ>?@AḄBC⏚ḄᔾFឋ⌱⚗A┯;BஹHIJឋ@KP2O5⏚ឋᓄᱥLὅᙠOPḄᩩRSTUV⌱⚗B┯;Cஹᔣ⛳YZᓄ[
\]HF^_ᑮᓄ[ab_ᑮc@⌱⚗C┯;DஹMgOdeTfg[F

15<~q
ᕈ⏚ឋᑣC(H+)>c(OH),j
\BqᜧvIc(CH3coO-)>c(Na+)>c(H+)>c(OH),⌱⚗C;D.V(NaOH)=20.00mLtL
ា_ᑮxᱥ0ḄBqḄo⏚YNaCl
ᵫo⏚᪷ᑖF<ᑣL
\c(CH3coO-)?(᝞)13ஹB

16ூ᪆௃A.CH3c(CH2CH3)2CH(CHj)CH3ḄÌÍ2,3-ÎᵬÐ-3-eÐÑÒA┯;B.ᵬÓpÂᐭÔ/ᓄÕÖ×rÂØÙ$ᡂẈÚ⁐ÛÜ.ᵬ⏚pÂᐭÝÈÔ/ᓄÕÖ×rqÞß⁐qrÂᐭàÈáÂØâ$ᡂẈÚ⁐ÛÜ.ℍ⃔åpÂᐭÔ/ᓄÕÖ×rqrᕈæß⁐.e⏚pÂᐭÔ/ᓄÕÖ×rqÞß⁐qrçÂàÈáÂØÛÜè$éêbpÂᐭÔ/ᓄÕÖ×rqÞëß⁐qrée⏣pÂᐭÔ/ᓄÕÖ×ríîB,-.C.ḂᓄcdðñGòᾦô⏚ᵞö÷ᙠ½ឋᩩùzḄbcdC┯;.D.qrúß⁐3GÜûüᨵ»$bÄ3GÜûýᑖbD┯;஺ᦑ⌱BoூBR௃ℍ⃔åqrpÂᐭÔ/ᓄÕÖ×r$ᡂæß⁐Ḅℍ⃔åÕqr.çqrÂØqrḄæß⁐þᜫ
ᡂẈ⁐Ḅᓄ஺14ஹBூ᪆௃ᔣḄZWYᐭ⏚!ᑮ#ᨵ%⁐ᡂ&ᨵ'()*ᕡḄ*,-.'()*ᕡḄ*,/ᓄ012/0ᓄ3ᑣWஹYஹZᑖ6/0ஹஹ3஺WஹXஹYஹZḄ78ᦪ:;/12,X?ᦪ@
X/ấᐗC஺A.D>EFᵫᜧᑮIḄJ8/Kr(Z)>r(X)>r(Y)>r(W),ᦑ┯NOB.ấ⏚/P⏚⏚/P⏚Q⏚Ḅ⏚ឋST⏚UT⏚Sấ⏚Uᦑ⏚ឋJ8H2SiO3ᓄᔠᱥᐸ]ᐰᵯYQᐸᵯY.Ḅ0᪷Y>#`ᵯYஹa`bcᙠᵯYe⊝;be⊝ᦑ┯NOD.ấgᡂD>ᨔ,gᡂᑖ>ᨔ,ᡠjấḄᰚlmnᦑ┯N஺ᦑ⌱Bo15ஹAூ᪆௃A.pH=5ḄNaHS(hp⏚ឋ,⏚᪷Y>ᵯYᜧnbrsY>tsᜧI:“HSCVAdSCV-AcCH2so3),ᦑA┯NOB.ᔣNH4clvᐭNaOHw,xpH=7,vᐭḄNaOHnNHKLᵫᵯ₹zឤKc(NH+)+c(Na+)=c(CI-),ᱥᧇ4zឤKc(NH+)+c(NH3H2O)=c(CD}~|c(NHH2())=c(Na+),NHyHhOᵯYᜧnNH4+bc(NH4+)>c(NHHO),ᡠ432Kc(Cl-)>c(NH+)>c(Na+)=c(NH3.HO)>c(OH-)=c(H+),ᦑBVWO42C.CH3coONH⏚᪷Y>;᪷Y>Ḅbrs@
ᕈឋNaClaᕈឋc(Na+)=c(C)

17C(NH4+)=C(CHJCOO"),c(CHCOO-)+c(Na+)=c(Cl)+c(NH+),ᦑCVWO34D.ᐭ30mLNaOH(pH>7),ᐸ20mL0ᓄ<⏚0Ḅ0Y>;ᒕḄ10mL0ᓄ<᪷Y>ᑣḄᨵO.OOlmolbᔠஹ0.0005mol⏚ḄpH>7,12bᔠḄᵯYrsᜧn╆᪷Y>Ḅbrs}~Jc(NH+)>C(NH•HO),C(OH)>c(H+),ᑣY432>tsᜧI/Kc(NH4+)>c(NH•H2O)>c(OH-)>c(H+),ᦑDVWO3ᦑ⌱A஺ூl௃⚪ὃY>tsᜧISஹ⏚ᔠḄឋᑨ¡¢⚪ᐵ¤K2W¥¦ᡂ§l¨ẚKª«¬ᵯ₹zឤஹᱥᧇzឤஹ®ḄbDᳮᙠᑨY>tsᜧIḄᵨ±²஺16ஹBூ᪆௃A.bµᴻXấ⏚Ḅb·ᵨn¸¹ᔠᑺ;■¼ᑺᦑAVWOB.T⏚0X½ᑴ¿lᡠᵨ⏗ᑺḄÁ⌕ᡂᑖ:ᦑB┯NKC.⏚⚞ÄÅÆᵨÇÈÉÊḄᑁÌᑺÍΓ⚞⚶”ᦑCVWOD.ÒÓḄÔDឋSÕஹ┯ஹஹÖḄÔDឋU·j<ᐸ×ᓄᱥØᣚ.ÚÒÓᦑDVWO⚪Û⌕Ü⌱Ý┯N⌱⚗ᦑ⌱B஺ூl௃⚪ὃᱥ¥Ḅᵨ⌶2Wᱥ¥Ḅឋ¥X⚪ᐵ¤ឋ¥àᵨ⌶ᵨ⌶,áឋ¥eª«¬âãᐗCᓄᔠᱥḄឋ¥ª«äẠ¡¢Ḅæç;èᵨ஺17ஹCூ᪆௃ᡃëìíîᜧ2Ḅ¼ï/“ðñòᩈô”“ᯚð”ᢣḄ/ð⏚3÷ᫀ/C஺18ஹDூ᪆௃Aஹᵫú·j¡⍝üýᵯ᩽¸ᱥ/CO2;N2,ᓄᦑa/ᵯÿḄ
᩽ᵯᱥH2,,ᦑbᵯḄ᩽ᦑA┯Bஹ▢᩽6H2O+6e-=6OH-+3H2f,□᩽6C-6e-=3CLTCO(NH)2+3CI2+H2SN2+CO2+6HCI,᪷2!"#$%&ᙠ▢ஹ□᩽ḄOHஹH+Ḅᦪ)*+□᩽,ḄH+,-./01ᣚ34ᐭ▢᩽6OH•ា9ᡂ;ᡠ$▢᩽,ᵯ=>?@ḄpHABᦑB┯CஹᵫD#$E⍝□᩽✌ᐜIJK0LᵯᡂJMJMNOᓄQRᡂSMஹTOᓄUVWXᡂHCL□᩽,ḄYZ6Cr-6e-=3CLTCO(NH)2+3CI2+H2ON2+CO2+6HCLᦑC┯2

18Dஹ᝞ᡠ▢᩽I6H2O+6e-=6OH-+3H2f,□᩽I6a--6e=3ChTCO(NH)2+3C12+HO=N2+CO2+6HCl,22L᩽ᐳᦈ÷ᑮ@0.6mol,øijn(N2)=n(C02)=0.6xl/5mol=0.12moLᵫCO(NH)2+3CI2+H2ON2+CO2+6HCI2TᡠὑḄCO(NH)2Ḅᱥ0ḄÉI0.12mol,ᦑD஺kᫀ⌱D஺219ஹCூ
᪆௃A.᪗úûüSÒ⏚I
@ýþÿ
ᦑA┯B.ᙠNChᑖNth2NO2:^^N2O4,ᡠ46gNOzᡠᨵḄᑖᦪNA,ᦑB┯C.ᓫḄ!ᙠ
"#Imol$ḄᨵINAḄ
ᦑC%&D.'ᓄ╅*+╅,-.
"#0."0.111101/5ᚈ஺2*+Ḅ282+ᦪ30.01mᦑD┯ᦑ⌱C஺20ஹBூ
᪆௃ᯚ⁐89⁐
:;<=!ᙠ>,
?@ᨵA,஺BᐭDEḄF⏚⚞*+IJ⁐KL
J⁐KLMᐰ*.ᙠO⏚
:;<=!ᙠP⏚᪷
R!ᙠS⏚᪷஺T+BᐭF⏚⏚ᓄḄF⏚UVᑮJ⁐KL
:;ᨵ',
ᓽ<=!ᙠNa+ஹCl,CO32,<=R!ᙠSth%?@ᨵK+
Yᫀ⌱B஺21ஹCூ
᪆௃A.ᵫ]?^
_ᑖḄ`ᓄ0—0aḄbcdC—OaḄᡂDf
ᦑA%&B.ᵫ]?^
ᱥḄh@EiᡂᱥḄh@E
"#j`ᓄ«(HCO3)>Ka(HClO),ᡠ2cH3coOH+Na2co3f2cH3coONa+HzO+CChTI
al2Na2cChHC1OR

C%&

19D.BᐭᑴḄCu(OH)2+⌕ᐜBᐭNaOHH2SO4,RᯠᑴḄCu(OH)2+S⏚
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D┯஺Yᫀ⌱C஺ூ¥¦௃Ka¨ᜧ
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᪷«ª⏚ᑴ¬⏚ᑣ
KaᜧḄ⏚?KaḄ⏚ḄOᡂKaḄ⏚஺sஹ®⌱¯⚪(ᐳ84ᑖ)23ஹ1-100nm2Fe2++HO2+2H+=2Fe3++2H2O´µEE¶·
ᵨ¹ᜮ»·»B〉EḄ½_ᓄ>*+
B¾2¶·
ᡂn¿ÀḄ⁐¶ÁÂḄ
ᑣÃ;Ä᪷,!ᙠÅÆÇÈᴻÊ2FeJ++3C10+100H=2Fe042+3Cl+5H02ூ.᪆௃ÌD*+»ᐭÍ-?VᑮF}ᑖᦣÏḄ⋎⁐¹
ᑣFFe(OH)3ஹDFe2(SC>4)3ஹENH4CIஹAᓫÏFeஹBFeSஹCFeSCh஺ூÑ.௃(1)᪷«¹Ḅ=Ò
⋎⁐½_ᓄÓ¹½_ᓄÓ¹xÔÕᜧḄ×ফCFeSO,Fe2+ÙÚ_-_ᓄ}Fe3+,Ḅ,Ûf2Fe2++H2O2+2H+=2Fe3++2HO.42(3)ENH4a*+
╆᪷,dÝ@lmÞ
␺=E╄᪷,ḄáâÛãä´µEE¶·,ᵨ¹ᜮ»·»B〉EḄ½_ᓄ>*+
B¾¶·
ᡂn¿ÀḄ⁐¶ÁÂḄ
ᑣÃ;Ä᪷,!ᙠ஺(4)ᑭᵨFeCh*+ᑴ´FeCb6H2Oᨔ
è⌕ézᒹëä»ᐭDEO⏚
ÅÆÇஹìᓾîᨔஹDT஺᪷«DTézḄïð]?^
DTéz◀òᧅஹôõ
ö◤⌕ḄÈᴻøᘤ}ÈᴻÊ஺মFeCbdKC1OᙠªÝឋᩩ?ᑴ´KFeO,Óᐗûᓄᔠýᵫ+3ᓣi}+6,'ᐗûᓄᔠýᵫ+1op}-1,24Ḅ,Ûf}2Fe3++3ClO+10OH=2FeO42+3Cl+5H2O»ÿ
ᔠ⚪⌕ᓽ)

20ூ
᪆௃ᙠᓄᑺᵨᡂC,Cᙠឋᩩ!ᡂF,FGᙠឋᩩᡂH,᪷#HḄ%᪀'()CḄ%᪀'(*;B(,-)ᙠᓄᑺᵨ./ᡂ!ᡂE,ᑣE*,⏣,⏣.2!ᡂ(CH3cH2)3N,#3ᑖ᪆6஺ூ
௃(D᪷#ᑖ᪆CḄ%᪀'(*EḄᓄ89:;,⏣;(2)᪷#ᑖ᪆ᙠᓄᑺᵨᡂC,!=>*!?B(,-)ᙠᓄᑺᵨ./ᡂ!ᡂE,!=>*/ᡂ!?NtCH:CHjhCl'(3)ᓄᔠᱥIḄ%᪀'(*,ᐸCDEFGHᨵ⏚KLM(4)A.ᙠ/Nᩩ!ᡂD,DᙠᓄᑺᵨOEEᓄᡂG,DPQR⁐TUDCDᨵVVWKᵫDᡂGḄ!YZ[\]ᑭᵨ᳛100%,%ᔠGḄ%᪀'()DḄ%᪀'(*\ᑣ`a!Ḅᓄ8ab(*c2+°22.(5)!CG('1)ᑮH(ebC\]fGᑖ]CῃhᑣaijḄklmDᨵnoḄpq%᪀lrTUdijᓄ8Kls?lsḄᓄ8K*ad
0(6)HḄ%᪀'(*t/\,Y*HḄwᑖx᪀yDᨵⅉp{p|}ᨵ~M

21!G!TUᑖ]CᵫMᨵMᦑ
ᔠ⌕Ḅ%᪀'(*25ஹᐵᜳ2ᑖᧅᮞ(ᡈᮞ)⁐2NH+3CUO_^_N+3HO+3CUCUO>3222Cu3a2+8NH3=N2+6NH4aூ
᪆௃(1)jA-EḄឋ⌕■yᐭF
(2)jBḄᵨ;¡¢2?(3)jCC£⁐¤y⌲¦§¨fEC⍎ª☢Ḅy¬®᣸ᐭ°TUEᓄ±.2!ᡂ±ஹ²ஹ;!Ḅ2ᐭE,P³ᕈឋᡂµ¶⏚·?(4)᪷#±ᐗ¹ºឤᑖ᪆¼ᱥḄᓄ8(?মjFC¼¾TUᨵᓄ¿ᡂ)FC.2!ᡂᓄ᪶²஺ூ
௃(1).ᐵᜳ2ᑖᧅᡭrᜳ1,ᙠECᐭᯠÃÄNA,ÅÆᑮECᨵÇᑈªÉr⏀ËÌECÍÎᨵÏÐᡂTUjឋÑÒ?(2)jBḄᵨ;¡¢2ᡠ¬BCÔÕḄÖᑺ;ᮞ?(3)jCC£⁐¤y⌲¦§¨fEC⍎ª☢Ḅy¬®᣸ᐭ°TUEᓄ±.2!ᡂ±ஹ²ஹ,!ab(;2NH3+3CUO=N2+3HO+3CU!Ḅ2ᐭE,P³ᕈឋᡂµ¶⏚ECḄZ2;×;ᨵ⁐ᡂ஺16g_(4)!Ø/i(CuO)=;^—;-=0.2mol,ᑣ/t(Cu)=0.2molஹn(O)=0.2mol
!ebC±ᐗ¹ᱥÙḄÚ§Eᐗ¹80g/mol

222.4gᱥÙḄÚÛÜ!äyÙÚÛÜ2.4g,ᑣÛÜEᐗ¹ḄᱥÙḄÚ;Ý~~-=0.15mol,ᒕà¤yC“(Cu)16g/mol“(0)=020.05=4:1>2:1,ᡠ¬`¤y¼ᱥḄᓄ8(*Cm஺ஹCu
মjFC.2!ᡂᓄ᪶²!ab(;3C12+8NH3=N+6NHC1O24ூâã௃å⚪ὃç2Ḅᑴᜓ.ឋÙYᒹëMåYìஹᓄ8íîïðñ2ḄឋÙஹUò2ᑴᜓḄ\ᳮ;⚪ᐵKônὃç8YGÝᑖ᪆GÝ஺26ஹCu+2Fe3+——2Fe2++Cu2+õᑖ(SCN)2.!ᡂ⏚FeJ++3SCN-Fe(SCN)³R⁐ö÷⁐3ᙠCM+.SCN-!C,CiP+;Eᓄᑺ,EᓄឋCU2+ு(SCN)20.5mol/LḄFe2(SO4)3³ᔠᳮú᣸◀E¡᡾~ýþÿ
A
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⁐ூ᪆௃(1)CuFe3+
!"#$%Cu+2Fe3+2Fe2++Cu2+
==(2)&'|(SCN”]:()*+ᓴ-
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<ᡂ⏚?(3)Fe2+A(SCN”4ᓄ%Fe3+,Fe3+KSCN
BC⁐?(SCN”DE4ᓄ
FGCM+E4ᓄ
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HᨵCu?+ᑣK⁐?(4)᪷M4ᓄNOPQᑖ᪆?মজAḄᵯ᩽%C,BḄᵯ᩽%Cu,ᑣCuVW᩽
CVX᩽
AYᵯ/?ঝḄ4[D\]?ঞ_ᓄ⍗abᑣ<ᡂc⁐஺ூd௃পCuFe3+
!"#$%Cu+2Fe3+=2Fe2++Cu2+,ᦑfᫀ%hCu+2Fe3+------2Fe2++Cu2+
(2)&KSCN”]()*+ᓴ-
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ᦑfᫀ%hiᑖ(SCN”;<ᡂ⏚?(3)Fe2+A(SCN)24ᓄ%Fe3+,Fe3+KSCN
BC⁐
!"#$%Fe3++3SCN-—=Fe(SCN)3
(SCN)2DE4ᓄ
FGCM+E4ᓄ,<ᡂ⁐
HᨵCM+ᑣK⁐,ᦑfᫀ%:Fe3++3SCN=Fe(SCN)3
l⁐
K⁐?(4)᪷M2C/++4SCN-^2CuSCN1(n⁐)+(SCN”(o⁐),CM+(4ᓄᑺ
4ᓄឋCu2+>(SCN)2,(SCN)2:4ᓄFe?+,ᑣ4ᓄឋ(SCN”>Fe2+,ᓽCM+s:4ᓄFe2+,ᦑfᫀ%:ᙠCM+SCNu
CiP+(4ᓄᑺ,4ᓄឋCu2+>(SCN)2iমজAḄᵯ᩽%C,BḄᵯ᩽%Cu,ᑣCuVW᩽
CVX᩽
AYᵯ/
ᑣᵯ/%0.5mol/LḄFe2(SO03
ᦑfᫀ%h0.5mol/LḄFe2(SCh)3?ঝḄ4[D\]
vV᣸4xy
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ᦑfᫀ%hzᔠᳮ?v᣸◀4[~᡾?

23ঞFe3+<ᡂFe2+,'ᓄ⍗abᑣ<ᡂc⁐
<ḄFe?+,xy%)G9
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஺2:ANaHSChᔾᦈ0.040.023CUSO43CuO+SO3t+2SO2T+O2T«ᣵBC,O2®ᐭE°±ூ
᪆௃(1)K;&⏚²ᙠ³ᩩµ¶:·<ᑖ
<ᡂ4ᓄ²ஹ¸4ᓄ&ஹ¹4ᓄ&74[
4ᓄ²%¥⁐?(2)EF(᣸;[¡¦[¤¤§
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ÄÅa&⏚EÆDANOᔾᦈÇÈÉÊ?(4)ºM<ᡂḄ¸4ᓄ&74[89Ëᙠᵯ!Ìឤ
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ºM&⏚²/ᣚ±ᱥ/Ḅ
Ðᔠ&ᐗ-Ìឤ°±¹4ᓄ&ᱥ/Ḅ?মºM(4)°±Óᑮ<ᡂᱥḄᱥ/Ḅ
ᯠᑏᓄ×"#$?(6)Ðᔠᵯ!Ìឤ7O!ÌឤØ
Ù⌕Ø⍝02Ḅᱥ/Ḅ
ᓽ°±SO27SO3Ḅᱥ/Ḅ
MÛᑖ᪆Ü᦮»¼஺ூ
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4[448mL(᪗ëìí)ᱥ/Ḅ%0.02mol,ᵯ!îï0.08mol,C11SO4SO228
°±Óᑮ¸4ᓄ&ᱥ/Ḅ%0.04moLºM&⏚²/ᣚ±ᱥ/Ḅ9.6P=1//------=0.06mol,Ðᔠ&ᐗ-Ìឤ°±¹4ᓄ&ᱥ/Ḅ%0.06mol-0.04mol=0.02mol
160g/molমºM(4)°±Óᑮ<ᡂᱥḄᱥ/Ḅᑏᓄ×"#$%3CUSQA3CUO4-SO3T+2SO2TW2T?4(6)ᵫ°±(4)ᑖ᪆Ø
Ù⌕Ø⍝02Ḅᱥ/Ḅ
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ᑣñᓄ"ᫀ(«ᣵBC,02

244ᐭE,ᓽ#᪷ᦈlḄOMmn஺28ஹ-746.50.01140%Eᔣ
qᔣO.lOMparூ᪆௃পtEজN2(g)+O2(g)=2NO(g)AH=+180.5kJ/mol,vECOḄwxy-283.0kJ/moI,#zyᓄ{q|":ঝCO(g)+yO(g)=CO(g)AH=-283.0kJ/mol,᪷ঝx2-জ#z2NO(g)+2CO(g)=N2(g)+2CCh(g)mn22&ḄᯚBAcফজ᪷V=mnᙠo-9minᑁWḄᙳ᳛v(N);2t▭ঝ᪷᳛=᮱r1°°%4mnঞ12minWᦋBᩩSMᜧNOஹCOᑣ⊝ᔣ
qᔣ¡¢£ᔠ¥ஹ¦§ஹஹ¨ᓄᑺª⊝Ḅ«¬ᑖ᪆¯ট᪷±ᔠ²³,ᡂᱥ´µ¶/ᱥᗩµ¶¹ᓄ{⊝ºᦪḄ*ªᜧ4ᑨ¼(3)ᑭᵨ¿À"n&⊝>ÁÂᱥ/Ḅᱥ/Ḅ/ᡂᱥ⊝ᑖ¦´µ¶◀$ᱥ⊝ᑖ¦´µ¶஺ூ௃পtEজN2(g)+(h(g)W2NO(g)AH=+180.5kJ/mol,vECOḄwxy-283.0kJ/mol,#zyᓄ{q|":ঝCO(g)+O(g)=co(g)AH=-283.0kJ/mol,᪷ঝ-জ#z2NO(g)+2CO(g)#N(g)+2CO(g)AH=2222-746.5kJ/mol,ᦑ¯ᫀ-746.5
-.0.2molr,4——O.lmol/Lফজ0-9minᑁNzBᓄ------=0.1mol/L,ᑣNzᙠ0-9minᑁḄᙳ᳛v(N)=--------------=22L9min0.011mol,L-I*min-,
ঝᵫDÅ#E9minWn(N2)=0.2mol,᪷q|"#EN2ᳮÇ0.5moLᑣ᳛Èᕨx100%=40%
0.5molঞᵫD#E2NO(g)+2CO(g)=N2(g)+2CO2(g),SMᜧNOஹCOᑣ⊝ᔣ
qᔣ¡¢A.LyᓣÌ¥⊝⌮ᔣ¡¢6DÅAÎᦑA┯B.ÏᐭNO,ᑣ"(NO)ᜧ6DÐA*ÎᦑB┯C.Ϩᓄᑺ⊝A¡¢ᔜᱥ/ḄABᦑC┯D.
ᔣI²¶Ḅ¦§ᑣ⊝⌮ᔣ¡¢NOஹCOᜧᵨᦑD┯E.LyÒÓ¥⊝
ᔣ¡¢6DÅ*ÎᦑE
ÔটᵫD#EÕ24minWn(NO)=1.4mol,n(CO)=0.4mol,n(N2)=0.3mol,᪷ᓄ{q|"#En(C€)2)=0.6moLᑣ

250.30.6,------X(z-------)2Ḅò⊝ôᦪ%h——¹)=0.69,÷NON2ḄFGøᑮOᩭḄ2ú
ᑣn(NO)=2.8mol,n(N2)=0.6mol,(ߟ)2x(—)2220.6,0.6,2—x(—)ᑣ——£—=0.34<0.69,ᡠßò⊝ᔣX"ᔣïý;(ߟ)2x(—)222বᵫCOḄᓄ᳛50%,:2NO(g)+2CO(g)^N(g)+2CO(g)22Ö×/mol2.01.000Øᓄ/mol0.50.50.250.5⊝/mol1.50.50.250.5—x3MPax(9x3MPa)2ᑣ⊝ᦪKp=-----------------------------*O.lOMPa(9x3MPa)2x(-^x3MPa)22.752.75ூ௃ᦋ᜜ᩩᑨ!ᓄ"⊝#$%ᔣ'᪷)*ᔠ,-./ᡂᱥ2345/ᱥ23457ᓄ"⊝ᦪḄ89ᜧ;<=ᑨ!>ᑖ@=B@xᱥCḄDᑖᦪ᪷)EḄᱥCḄDᑖᦪFG⊝ᦪ4-I-1-ூJ᪆௃(1)AᑖL9MN᪀ᑖL.Pᨵ3RSTLᐸ᪶WᐳYSZᐹᨵ3\ᔾᦈ_>9`BஹCḄN᪀bB.c-0HdḄHefgB-CḄhifg>ᵫEḄN᪀bPᨵḄjklᨵmnஹop>DPᨵqrஹsstp,kv/wᡂPᨵcmn'v/fgcmnஹsstpᙳkv/yᓄzkv/{|ᦑ⌱ট>ᫀ3fg>mnஹ⏚p>ট;ফ9`AஹBḄN᪀bA-BhifgᑣXCH2=CH(CH3)CH2C1,ᨵHC1/ᡂ%(3)YXḄᑖ᪀,ᑖL.zPzPᵬnᑣYCHI=CHCHCH2C1,-4-IT-;2

264জCzPcmnDPᨵcmnkIᓄv/⁐'ᵨIᓄ␺¡C7D,ᦑজ£¤>ঝCPᨵopஹDPᨵcmn¥ὅPᨵjklz§ᐰᦑঝ┯«>ঞCஹDᑖL8N᪀z¬ᑖ᪀,ᦑঞ£¤>টCஹDᙳPᨵsstpk®v/wᡂᙳk¯°±²⁐ᦑট£¤>ᫀ⌱জঞট>5EḄ³✏µᑖ᪀,¶·Pᨵ¸nkv/¹ºPᨵᵬ⏚»ᡂḄ¸nrdḄ¼Igᱥ½ᨵ¼RNᔠEḄN᪀bPᨵ4¾ᵬn9MN᪀¿ᔠᩩḄᑖ᪀,:ூ௃À5ÁÂPᨵ¸nkv/¹ºÃÄᵬ⏚/ᡂḄ¸nrdḄ¼Igᱥ½ᨵ¼RᡈὅÆǼÈÉÊËÌ9MḄN᪀'ÍẚÏ⚪஺