浙江省杭州2021-2022学年高三六校第一次联考化学试卷含解析

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9ঝPQCO32-ᙠ▢᩽I:@ḄTᳮ,VὃXᫀZஹ⌱\⚪(^⚪_ᨵZa⌱⚗cᔠ⚪C)1ஹAூ=᪆௃ᵫD+J@CH4+CO2qi^2CO+2H2,Niiᓄᑺkᓄ%&lᨵᓄmḄnoN@ᡂজZঝqrstᩭ=X஺ூv=௃A.জZঝlwxyqrsᦑA┯|
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10Aஹa^ᜐT]B_ᨵSO42-,`ᐭBaCL,bcdBaSChe⁐ghᦑA┯kYBஹpHᓣmnoT]c(H+)pqr(Sthz-)sᜧtFusᜧᢥ᯿xyFNdᡂH+,T]c(H+)sᜧ,T]ḄpHJpq|bsᜧᦑB┯kYCஹc^T]BFe3+~SO3?dtIJFN2Fe3++3SO32-+6H2O=2Fe(OH)3I+3H2sO3,ᦑC;DஹT]`NaOHbὑT]BḄFe3+,⁐JᦑD┯kYᫀC஺3ஹCூt᪆௃A.10mLO.lmolIFNa2cO3T]⌲`ᑮ10mlLO.lmol-L-1⏚Bcdᓄ`⏚ᐰIJ⏚Eᡠ¢£ᑮ⏚~¤ᓄḄ¥ᔠᱥᡠ¢§uᜧqc(Na+)>c(Cr)>c(CO32-)>c(HCO3-),AYB.ᵫ4K(CH3COOH)>K(HClO),CUTtFuᜧ4CH3CO6tFu©ªT]BḄ▢ḄᱥḄ§u¬~:aaঝ>জBC.ᔣO.lmol/LNH4aT]BNH++HO^NHyHO+H+,`ᐭ¯NH4cl°NH+,NH4+t±⊝ᔣ4224c(NHY)c")·¸C(NH3-HO)>C(H+),t;ᦪ|ᓽ—,NH4+tFupq,pq,2ὡ½¾ὡ)(c(NH)c(NH)ccrD.Ksp(AgCl)>Kp(AgBr),ᙠAgCl~AgBr©⛳~T]BÁὅc(Ag+)ᜧ4ὅc(Ag+),c(CI)>c(Br),ÃÄAgCkAgBr©⛳~T]¥ᔠdghḄÅᓄdᡂÆÇḄAgBrghÈÉT]Bc(C1)ÊrᩭAgCl⛳~T]BᜧÃ`ᐭËḄ§AgNChT]AgBrghᨵᡠsÇÌAgClghs`ÆÇDYᦑᫀC஺ூ^Í௃Ã⏚⌲`Na2cChT]|cdᓄÎḼ⏚EÐcdᓄᐸIJFNNaCO+HCl=NaHCO3+NaClNaHCO+HCl=NaCl+HO+CO2T23324ஹBூt᪆௃YÈMÒᡂḄ᝱ᓄᔠᱥᙠ᪗ÕÖ×PḄØu0.76g-L-1,Ù᝱ᓄᔠᱥḄ᥅Û22.4L/molx0.76g-LT=17g/mol,ÙNH3,MஹXஹYஹZஹWܪÝᕜßᐗáârãᦪäåsᜧᑣMHᐗáYNXஹYஹZᨬ᜜éᵯᦪ¬~15,XÈZëÒᡂXZ2ᑖX+4íY-2íëîyXஹYஹZᑖïCஹNஹOðªᐗ

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B.XஹYஹZᑖØCஹNஹOÆÁᐗ¾ÙÚÛឋX?ᨬ@AB9CᔲDEᨵso-ᓽCH+D.⏚ITeCh3JK@LNa2sMNTe(hOᡂTeᓫRSOOᡂSO,ᡠH+ḄSTU#VWX2SO-+TeO=2SO^+Te4<,TeChᓄᱥSTU#VghᑖD┯஺2jᫀ⌱C஺6ஹBூ
᪆௃A.ᔣop-ỚᓄrḄ⏚ឋ3ᐭuH2O233vᓽwxyOXH2O2+2I-+2H+T2+2H2Oz{H2O2ᐹᨵᓄឋ}ᔣx⁐3᠒ᐭḄSO2,x⁐⌲ᜫyOXSO+l2+2HO=SO42+2I+4H+,z{SO2ᐹᨵ22MNឋᡠH2O2SO2Oᡂ⏚W⏚ᦑAH+B.}ᔣx⁐3᠒ᐭḄSO2,x⁐⌲ᜫyOXSO+l2+2HO=SO42+2r+4H+,-SO2ḄMNឋ,22ᦑB┯C.S02ḄᵯT!ᦪ=2+(6-2X2)=3,ᵯTᦪW1,NTsp?ᩖᓄᑖTWV᪀ᦑCH+D.H2O2ᑖT0-0W᩽ឋO-HW᩽ឋH2O2⚓¢᪀ᱥR᪀£H¤ᵯ₹¦§ᔠW᩽ឋᑖTᦑDH+

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᪆௃A.°ᨬ᜜7!ᵯT²᧕'ᑮᵯTNaᨬ᜜1!ᵯT²᧕ᜫ´ᵯTSi᧕ᜫ´µ᧕'ᑮᵯTB.¶·ឋḄᐗ¹ᓫRgº¶·ឋ»Ḅ¶·ᡂḄ¼½ᣚ¶·ᓫRC.ᔣNa2sCh3¼⏚yO⏚ᑴ»⏚ḄD.¶·ឋÀ;ÁÂᓄᔠÀ²᧕஺ூ
௃A.°ᨬ᜜7!ᵯT²᧕'ᑮᵯTNaᨬ᜜1!ᵯT²᧕ᜫ´ᵯTSi᧕ᜫ´µ᧕'ᑮᵯTᡠ°;Ãᡂ°ᓄÃEᨵST°;ấᡂÅ°ᓄấEᨵᐳᑭᵨᐗ¹ᕜÉÊJËᦑA⌱B.ᔣopKI3ÌᐭÍÎ3wxz{ÏᓫRḄᓄឋÐỚᓫRgᵨᐗ¹ᕜÉÊJËᦑB⌱C.ᔣNa2s033¼⏚yO⏚ᑴ»⏚ḄHC1ᨬÑE⏚gᵨᐗ¹ᕜÉÊJËᦑC⌱D.¶·ឋF>LᦑÒÂ;ÁÂᓄᔠÓ²᧕ᑭᵨᐗ¹ᕜÉÊJËᦑD⌱ᦑjᫀ⌱Co8ஹCூ
᪆௃AஹÔᨵÌᐭ¼⏚IMOHḄAG=-8,ÕÖ2_=1஺4᪷ØÎḄSTÙKw=c(H+)xc(OH-)=10-14,Jc(OH)=10cCOHJ-3mol-L_,,56MOHW»ÚᵯSU#VWMOH=M++OHᦑA┯BஹCªIAG=O,ᓽC(H+)=C(OIT),3ÛឋMOHW»Ú3ÛឋI6I3RWMOHMCL56ὑHC1Ḅ-ÙÝÐ10mL,ᦑB┯;CஹBªᐭ¼⏚3Ḅ-ÙW5mL,6I33RWMOHMCLßàὅᱥRḄâã᪷Øᵯ₹äឤᵫc(M+)+c(H+)=c(Cr)+c(OH-),᪷Øᱥᧇäឤc(M+)+c(MOH)=2c(Cè)àVᔠê'ᑮc(M+)+2c(H+)=c(MOH)+2C(OHA),ᦑCH+DஹKḼHC1ḄÌì̼⏚Ḅ-ÙW10mLIÎᵯS#í⌲îᜧì¼⏚ÎḄᵯS#íðᑮᢓᑴᦑD┯஺9ஹAூ
᪆௃A.òXWóôYõᡂNᵯö÷øùH᩽Lúûgüý÷øùḄῖ⇨᳛ᦑAB.XḄᵯ᩽Fe-2e=Fe2+,ᑣ᩽ῖ⇨ᡠḄῖ⇨᳛ᦑB┯"

13C.X%&ᵯ'()᩽▢᩽Ḅῖ⇨᳛ᦑC┯"D.X%&ᵯ'()᩽▢᩽Y᩽□᩽ᑣY᩽,-.ᓄᦑD┯"ᦑ⌱1Ao10ஹCூ4᪆௃A.78B9:;CaCL<=ᑺ<=NO?@ᵫB78UCDᣚFG⏚?@IJKLMB9ḄNOᣚFG⏚A┯"B.PQRSTIUVWXCO2,Y᣸[789Ḅ\?]^NO.ᓄ_-N(h?@,-2N(h+Na2O2=2NaNC)3,`CO2a,-12co2+2Na2(h=2Na2co3+O2,KLbᑴdefghḄNaNCh,B┯"C.RSijkl⏚WA9Cumkl⏚_-NO?@NOm789Ḅ02_-Nth,KLaᨵopqr⁐?@CD.ᙠ78D9NOa⏚ឋKMnOavw.ᓄxvwy⁐KLzD9vw{q⁐|}~NOY.ᓄ,LW~Yijkl⏚D┯"ᦑᔠᳮ⌱⚗C.11ஹDூ4᪆௃A⚗NaHCChmHC1NaHCChᵨBᑴ⏚9ᑺNaHCChᵨBᑴ⏚9ᑺmNaHCCh᧕ᑖ4ᨵᐵB⚗Si(hᐝḄᵨBᑴᐝSi(hᵨBᑴᐝmSiChᰚᜧᨵᐵC⚗ALChḄᰚ¢ᵨὊ¤ᩞᧇALO3ᵨὊ¤ᩞᧇmAWh§ឋ.ᓄᱥᨵᐵD⚗CaOm;ᵨB©O<=ᑺCaOᵨB©O<=ᑺmCaOm;ᨵᐵªᫀ⌱D஺12ஹBூ4᪆௃᪷¯°±.ᓄ²vw-ᡂ´?´?xµ¶Ḅq⁐·¸¹º|»⁐ᑣ◤⌕q⁐·¸¹º¾◤⌕¿À;¶µ¹ºᑣ◤⌕ḄᱥÁ»⁐·¸¹ºÂkG⏚টঠᦑªᫀB஺13ஹCூ4᪆௃AஹjᐭCCL,Æ₩ஹ☟8ÉÊË{q⁐Ì5mL0.05moi/LFeCbvw9jᐭ5mL0.05mol/LKIvw§ὅ,-.ᓄÎÏ-ᡂỚᓫÁᡠḄᓄÒÓÔ12Fe3++2IP2Fe2++l2,ᦑABஹII9ÉÊË᩽}Ḅ{⁐Ìjᐭ⛳KSCNvwÖ⊝2Fe3++2r=2Fe2++L⌮ᔣÚÛᡠᙠ⛳KSCNvw9ỚᓫÁ.ᓄᑺ¯°.ᓄ_ᱥ᪷Ü.ᓄᑺḄ.ᓄឋB.ᓄ_ᱥḄ.ᓄឋᑣ.ᓄឋ1II9I>Fe3+,2

14ᦑBCஹaÝÞ¯°mỚ¯°-ᡂᓫÁỚ߯°àbÝÞḄ¯°mKSCNvw-ᡂáᔠᱥḄ§ὅâ:ãefᐸÔḄᜧåᦑC┯"DஹII9ÉÊË᩽}Ḅ{⁐ÌÖ⊝2Fe3++2r=2Fe2++L⌮ᔣÚÛæ߯°ḄFçåHI9ᔣèUéjᐭCC14,ỚᓫÁv4ᙠêëᓄì9ỚᓫÁḄFçåÖ⊝2Fe3++2I-=2Fe2++LᔣÚÛᡠ;vw9c(Fe2+)IIVm,ᦑDªᫀ⌱c஺14ஹDூ
᪆௃A.᪷ÜíîYïজᡠñvw9òᨵóFḄô⏚²ô⏚vwË⏚ឋÌô⏚Ḅᵯ¯ÔᜧBô⏚᪷Ḅ;4Ôõ!Jc(CH3coeT)>c(Na+)>c(CH3COOH)>c(H+)>c(OH-),A┯"B.ঝᡠñvwË9ឋᑣ᪷Üᵯ₹ùឤYïc(Na+)+c(H+)=c(CH3CO(T)+c(OH-),B┯"C.ঞᡠñvw9üὅាþ-ᡂḄô⏚²;4vwËÿឋ
ᑣc(Na+)>c(CH3COO-)>c(OJT)>c(H+),C┯CóCHC0QHD.⊤⏚ᵯ⊝ᦪḄ᎔ᦪ
⊝ᦪᨵᐵ
ᙠ᦮!"#$%"ôQi3co0-•õg
CHC00H&'()
D*+஺[CH3co0ö.õ-ᫀ⌱D஺15ஹCூ
᪆௃Aஹøᓄù|úøᓄû⌱⚗A┯kYBஹ|údþIJ⌱⚗B┯kYCஹ-OHÿC
ᨵHᨵ-CH20HḄ᪀ᓄ⌱⚗CDஹᓄᓄ⌱⚗D┯஺"ᫀ⌱C஺16ஹAூ
᪆௃A⚗
23ᓄ5ᑖ789᩽ឋᑖ7
;8ᵫ=5>7?23>7@᩽ឋᐳBCDᔠFᡂ
ᑖ7HIᕈ☢2LH
5>7M"
CL120஺
ᦑA⚗┯B⚗
ᙠNH,+?Cu(NH3)4P"QRᙠSTC
Uὅ8W>7XYSZᵯ7Z[\>7
]ὅ8^>7XY_`⍝
ᦑB⚗*+C⚗
ᐗcḄ>7ᙠᓄᔠᱥ"eᵯ7ᔾgᔣijḄk⚞mnᐗcḄᵯoឋ
ᡠqᵯoឋrᜧḄ>7
ᔾgᵯ7Ḅtu

15rw
ᦑc⚗*+D⚗
>7ᨔy">7qᐳBCDᔠ
=z>7ᨔyD᪀Ḅᱥ|CtQ}~ᜧஹᰚ}~ஹ}~ᜧ
ᦑD⚗*+஺-ᫀ⌱A஺ஹ9⌱⚪(k⚪ᒹ5⚪)17ஹCU(NO)24NO2+O2+4OH-=4NO-+2HO3CUO+2NH=3CU+N+3HOCU(OH)6(NO)2^CU(NO)3323224332■3CU(OH)2NO2ᨵ3ᓄឋ
Na2s2஺4"+3BḄ5ᐗcᐹᨵ>ឋ
t3ᓄ>ூ
᪆௃ZX]ᑖP⁐Ḅᔠy
ᔠy"=ᨵN(h,ᡠqX"=ᨵN?OᐗcXᑖPḄ⁐yN%]
q¡¢⁐y
ᓽ^ᓫ|
ᡠqX"=ᨵCuᐗc
ᡠqX¥CU(NO3)2஺ூ
௃(1)@ᑖ᪆§
XḄᓄ¨©ᓽ¥CU(NC>3)2(2)@ᑖ᪆§Cu(NO3)2ᑖḄª!©¥#2CU(NC>3)1=2CUO+4NO,T+O,Tᡠqᔠy«¬NaOH$%Ḅ7ª!©¥#4NO+O+4OH-=4NO+2HO222(3)@ᑖ᪆§⁐yYᓽ¥CuO,ᐸNH3Ḅª!©¥#3CUO+2NH=3CU+3HO+N522(4)0.1molWt®ὑ0.6molHCl,ᡠqWᓄ¨©"°ᨵ6OH±¥,O.lmolWᑖ¡ᑮY(CuO)|¬32.0gᓽ0.4mol,ᡠqWḄᓄ¨©"°ᨵ4Cu2+,ᡠqWḄᓄ¨©¥CU4(OH)6(NO)23(5)ᔠy"°ᨵNO2,ᐹᨵ3ᓄឋ
ᐸqᐹᨵ>ឋḄNa2s2O43ᓄ>
´Fµᓄᡂ¶·ḄN2஺18ஹ(1)¸¹
CHs(2)ᡂ
º»(4)cd(5)18(6)CH3CH2CHO,OHC-^_y-CHO஺ூ
᪆௃᪷½¾¿ঝ
ÁÂC?DD᪀é¥#CH3CHO?CHO,AḄᑖ7¬¥28,ÁÂA¥CH2=CH2(¸¹),B¥CH3cH2OH,GḄD᪀é¥#^Q^-CHO,FḄD᪀é¥#CHQH,EḄD᪀é¥#a^O^~CHC1,DḄD᪀é¥#,ூ
௃

16(1)A¥¸¹
DḄD᪀é¥#(2)A?BCH2=CH2+H2OÄÅRCH3CH2OH,ᡂ
CḄD᪀é°ᨵÆtÇ8º»;H(0(3)EᡂF,ÉÊ
ª!©¥:CH2CI+NaOH--------CH20H+NaClA(4)᪷½GḄD᪀é¥:CHO,aஹÌÍ°Î\ÏÐᐗc
G"°ᨵOᐗc
ᦑ┯bஹ(°ᨵÑÒ»
FeCb$%(Ó⁐
ᦑ┯cஹ°ᨵº»
ÔᑴCu(OH)2ᐳPCU2O,ᦑ*+dஹÖ×8☢*ØÙH
º»ᐳ☢
ᡠᨵ>7ᐳ☢
ᓽᨵ14>7ᐳ☢
ᦑ*+CH=CHCH3(5)NḄÚZᑖ7|¬}Mᜧ14,ÛÜN}MÝ=“CH2”,(ÞßZ2Ð)ஹàÞCH0ßZ2Ð)ஹ(ÞßZ2Ð)ஹ(ÞßZ2Ð)ஹ(ÞßZ2(ÞßZ2Ð)
ᐳᨵ3x6=18Ð;(6)᪷½¾¿ঝ
X¥CH3cH2CHO,YḄD᪀é¥OHC19ஹ2KMl104+16HC1=2KCl+2MnCh+5CLT+8H2OᡈKClOj+6HC1=KCI+3cI2T+3H2O2SCL+2H2஺=S+SO2T+4HCIãᑴᑖ%äᧅḄæç
èéê⏚ᒴìíîᐭᰚð5Ḅíª
èñ5ᐙᑖóôஹ
õöñ¬FᡂSC12◀øSC12ùᨵᔾᦈC12ஹSC12ûüḄýþூ
᪆௃(1)জ
ᩩᵨKMnOᡈKClOjHC1ᵨᑴ4ঝSCL(2)Ḅᑴᑖ!ᧅḄ#$%&⏚ᒴ)*஺(3),-ᑴᑖ!ᧅḄ#$ᩭ/⁚Ḅ1᠒(4)SC12Ḅ34559'C,60C6ᓄ8◀:(5)CLஹSCL<=ᨵ?@AB᛻஺ூ
௃(1)জ
ᩩᵨKMnOᡈKC1OHC1ᵨᑴᓄEFGH2KMnOI+16HCI=2KCl+243

17MnCh+5CLT+8H2OᡈKClOj+6HC1=KC1+3CLT+3H2OঝSCLK2SCL+2H2O==S[+SO2T+4HC12
Ḅᑴᑖ!ᧅḄ#$%&⏚ᒴ)*஺3
CLMNOPQMRᰚTUVFW☠Y☢[ᐭᰚTUḄF%Uᐙᑖ^_ஹ`ab-c8ᡂSCL஺4
SChḄ34559࠷,60C6ᓄ8◀:஺DLMNe60࠷
Ḅᵨ5◀:SCL5
CLஹSCL<=ᨵ?@AB᛻஺LMDfgᙠḄi4KjᨵᔾᦈCLஹSCL<=ḄLM20ஹNH+HC1=NHC1mn34op᧕ᢵbC6HNH*+OH——>C6H5NH2+H2Ostᱥvᔠ3453ᱥx◤ᑴz{■}BN~᎔ᔾ60.0%
ᐭ&⏚ᑖ◀:m
ᐭᓄᑖ:
ᐭNaOH~ஹ-ூ
᪆௃ᑴᜓmnKᔣm┱vᔠᱥNᑖᢇ
ᐭ-cḄ&⏚ᡂmnᑖᢇ
ᐭ&⏚■}ᒓ`abᢵ8⌼ᡂḄᜫW-cḄ&⏚mnᡂC6H5NH3CL
ᐭNaOHC6H5NH3஺ᡂmn஺ூ
௃1
ᑖ↾ᨵ&⏚Ḅᴻ¢☠Yb£ὅ¥ᨵᢵឋᙠ§N¨⍗6ᡂNH4aª⁐~ᦑª®FGHNH3+HCI=NH»Cl¯°⊤N²³mn34op184࠷
,᧕ᢵb´ᵨmnµ¶·¸ᑮª®2ºNᳫ¼½¾QḄFᔣ“OVt”ᓽ“bOat"ÃfÄŽ¾Qᑁᐙǽᓾᐙᑖ½¾ḄᦔÊ3-c&⏚mnᡂCAHSNHJCI,%ᑴËÌᔣÍÎᐙᑖ
ᐭNaOH%C6H5NH3clᡂC6H5NH2,ÏÐFGHC6H5NH+OIT=C6H5NH2+H2O4ᵫRstᱥmnḄvᔠᱥᦑx◤ᑴz{5ssÒLMNÓᯠᨵᴻQ⊝Ö×5ᙠØ▭Ú6LMᑁḄÖÛᯠᜧR᜜ÞᜧÖß᪵sÃfOᐭá⚠ãäNᡠss✂çèᙠËtãäCéêëᐜᡭî}ᜳd,ð}
■}LMᑁÖñòᯠ`óôõ᎔ᔾ6
ö÷mḄᵨc5.0mL,ø{L23g/cm3,ᑣmḄúc6.15g,ᑣmḄᱥúḄc[Ko]=0.05mol,᪷°FGH÷ᳮ
ᡂḄ0.05mol,ᳮ93g/molxO.O5moi=4.65g,▭279g,ᡠ᳛igx1஺஺=60.0%“”ᓽ᣸◀ᵨḄ!"◀ᩖ$%&HCI'()*$
ᡂ+',-ḄCeHsNH3a./0ᑣ%&HC1'()*$2',-஺ᡠ+ᙠ4ᔠᱥ7ᐜᐭ:;⏚$=ᑖ(◀?/0$@A-'(7NaOH'(᪆

18C$ᑖ(DᵨNaOHEFGH7IJᨵḄL-ᑖ$M?NaOHEF$ᓽ+NOPQḄ஺ூST௃-VWᙠX'ᡈ',-ḄᨵZᱥ7[ᐭ-Vᐳ$]ᨵZᱥ^-V_`Cᩭ$WᑖbcdPᨵZᓄᔠᱥḄfᵨ!"஺21ஹ2a+2b+c0.021hiBC1050Kj)*klᑮn⊝p᝱$^Ḽstᓣv$)*w᳛x$NOyᓄ᳛zᜧ20%440HMe=2H2O+O2T▢᩽-ᵯ
ᡂVc᪷b$OIT&HCCh-)*
ᡂCO23ூ᪆௃পᑭᵨ஺ফজ᪷02nᙳ)*w᳛ᓣvst$n⊝ᔣᔾ)*ᓽ⌮ᔣঝA.ᐭ_Ḅp⏚┛,n⊝$tB.[ᐭ_Ḅ02,n⊝¡ᔣ$¢ᓄtz$Vt£¤¥ᩭzC.〉§i¨ᘤḄFª$«ὅtᙠ¥ᩭ0Ạ¯z$n⊝ᔣFªhi!ᔣᓽ¡ᔣD.ᐭᔠ〉Ḅ°ᓄᑺ$n⊝$t஺(3)1050Kj)*²Ḅ¡ᔣ³´n⊝$µ¶NOḄyᓄ᳛^stᓣv.zᜧ³´·¸¹º஺(4)³´·¸»¼n⊝fᦪ஺(5)জᙠ□᩽¿W᪷ᜫ?ᵯ$Á
Ḅ)*ᒹÃ4OH--4e-=2H2O+O2f,ᒕÅbc⏚᪷)*ঝ▢᩽-ᵯ
ᡂV$ᒕÅ᪷b$ᒕÅḄOH-&HCO3-)*
ᡂC(h2-஺ூÆ௃প᪷Ç᪗)*$ÉÊ_Ë!Ì2ÍÊ¢Ë!Ì2Í@Ê·Ë!ÌNᑮÎ)*2SO(g)+4NHyHO(aq)+22O(g)=2(NH)2SO4(aq)+2HO(I)ḄAH=(2a+2b+c)kJmol1242(2)জ0lOminᑁ$(hnᙳ)*w᳛u(O,)=ᒹ=$=஺ozimoll?♦minTᓣvst$n⊝At10minᔣᔾ)*ᓽ⌮ᔣ$µ¶Ð)*Ḅn⊝fᦪKhiᦑÒᫀÎ0.021hi஺ঝA.ᐭ_Ḅp⏚┛$n⊝$t$ᦑAÔᔠ⚪ÖB.[ᐭ_Ḅ02,n⊝¡ᔣ$¢ᓄtz$Vt£¤¥ᩭz$ᦑBÔᔠ⚪ÖC.〉§i¨ᘤḄFª$«ὅtᙠ¥ᩭ0Ạ¯z$n⊝ᔣFªhi!ᔣᓽ¡ᔣ$ᦑCÔᔠ⚪ÖD.ᐭᔠ〉Ḅ°ᓄᑺ$n⊝$t$ᦑDÔᔠ⚪ÖׯᡠØ$ÒᫀBC஺(3)ᵫÚ+Û$1050Kj)*²Ḅ¡ᔣ³´n⊝$µ¶NOḄyᓄ᳛^stᓣv.zᜧ$ᐸ¥µ1050Kj)*klᑮn⊝p᝱$^Ḽstᓣv$)*w᳛x$NOyᓄ᳛zᜧÝÞßàNOᨵImoLᙠHOOKà$yᓄ᳛40%,

19C(s)+2NO(g)G=-N(g)+CO2(g)256(2mol007ᓄ(0.8mol0.4mol0.4mol8⊝(1.2mol0.4mol0.4mol0.4molCO2ḄFªᑖᦪ3=x100%=20%ᦑÒᫀ1050Kj)*klᑮn⊝p᝱$^Ḽst1.2mol+0.4mol+0.4molᓣv$)*w᳛x$NOyᓄ᳛zᜧ20%»(4)ÝÞßàNOᨵImol,ᙠ1050Kà$yᓄ᳛80%C(s)+2NO(g)â_N(g)+CO(g)2256(2mol007ᓄ(L61noi0.8mol0.8111O18⊝(0.4molO.81110I0.8moll.lxlO6Pax—xl.lxlO6Pax—Ð)*Ḅᓄãn⊝fᦪK,=---------------------------------------2=4ᦑÒᫀ4஺(l.lxlO^ax-)22মজᙠ□᩽¿W᪷ᜫ?ᵯ,Á
Ḅ)*ᒹÃ4OH--4e-=2H2O+(McH++HCO3=CO2T+H2OᦑÒᫀ:4OH--4e-=2HO+O2To2ঝ▢᩽-ᵯ
ᡂV$ᒕÅ᪷b$ᒕÅḄOH-&HCO3-)*
ᡂCO32-,µ¶▢᩽¿@
CO32-;ᦑÒᫀ:▢᩽-ᵯ
ᡂVc᪷b$OIF&HCCh-)*
ᡂCO?o