浙江省绍兴市绍兴2021-2022学年高三第三次测评化学试卷含解析

《浙江省绍兴市绍兴2021-2022学年高三第三次测评化学试卷含解析》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2021-2022ὃᓄᔁ⚗1.ὃ⌕ᑏὃ஺2.⚪ᡠᨵᫀᡈ"ᑏᙠ⚪ᓱ%&ᙠᔁ%'(ᦔ஺*+,ᑖᵨ2B/0'1*2,ᑖᵨ3⁐56Ḅ850'஺3.ὃ9:;&ὃ<ᔁ⚪ᓱ=ᙠ>☢%&@AὃᕒᦈD஺+ஹ⌱G⚪HI⚪Jᨵ+K⌱⚗Lᔠ⚪N1ஹOPQRSᳮᡈU'VWXḄYA.ᯚ⁐[\QRV&]^ᙠ↾`@abcd&\ᐜᵨfH2s04ghijkB.ᑴᜓnoᓄpqrcs&ᔣ10%NaOHbcVuᐭwx2%CuSO4bcC.yᑴzH2so4ஹzHNO3{ᔠ⏚s&✌ᐜᔣ~=ᐭ+xzH2s04D.%ᓣ᪆QRV&<cuᙠᑺ&☟2ஹGiGaGsBrY*ᕜḄᐗ஺Pᑡᑖ᪆WXḄYA.S:Br>Ga>Cl>AlB.ᐗ*ᕜ*WAᐗC.793sBr8%Br¢ᵯ¤¥¦§D.¨ឋ:Ga
OH3>Al
OH3,⏚ឋ:HClO4>HBrC>43ஹᑭᵨ«¬QR®¯ᡂ±²QR&ᐸV¦¤´ᑮ¶\QR·ḄḄY⌱⚗ᑺ1ஹᑺ2QR·ḄAÅxÆÇஹÈÉbcaÈÉVÉ⏚zÊBËÆஹÅxfÌ⏚aËÆHÍᨵ¦Î[\ḄᩖÐNÑÊCÒ⏚ÓÔÕஹÖ×ØÒ⏚ÓÖÙᔾÛDÅoᓄÓÔÕஹÖ×ØÅoᓄÓÖ[\ÜÝÕA.AB.BC.CD.D4ஹPᑡbc+ᕈVឋḄYA.c(H+)=c(OH)B.pH=7C.K=1014D.c(H+)=107mol/Lw5ஹ᪷¹⊤V»¼Ḅ½¾ᑨÀPᑡÁÂ┯ÄḄY

1ßàá[\ḄᱥÐᡂᱥজMnCh+ஹCä…Ch,Mn2+-ঝCb
wxNஹFeBrFeCbஹFeBr23ঞKMI1O4ஹH2O2ஹH2SO4K2so4ஹMnSO...4A.*জß[\Vᡂ().5molCL,èéImolᵯB.*ঝß[\VÎá[\ḄCLFeBrzḄᱥÐḄxêë1
2C.*ঞß[\ḄᐸìÜᱥ02H2OD.oᓄឋᵫîᑮïḄðMnO>Ch>Fe3+>Br246ஹñòYñÖó9ôᡂḄõÖò஺ñÖó9s&,ᑖᩭ¦÷øùḄúᑖOᓴüḄýþÿᒹ
ᙠᨔᡂ“”(ᎷᑖNaCl)ᐸᜧ᪀᝞ᡠ!"Ḅ$%ᑮ1'()ᓄ+Ḅ,-.,஺ᑡ1234Ḅ5()0^00*^0o0Qoo0^owwww᜜y0^yI0^00^00A."ᑁ7“”89:;8⌕NaClᑖ@ḄABᙠD."ᑁ7NaClḄC;D-lO^mol/L(Ḅ:;-0.9g/cm3)7ஹᑭᵨGHᢈJKLLC;M⏚OPQḄpHRS;(T)ḄᐵUVW᝞ᑡᑖ᪆┯ZḄ5A.M⏚O,[5ᔾ]^_B.ab`ab,[c⊝3ᔣfg

2C.be`ab,[c⊝⌮ᔣfgD.,Ḅᵯkc⊝lmpHnopq8ஹsᑁtuᢈẆw

3A.MÜPQÅ:c(Na+)>c(HX-)>c(H2X)B.PÜPQÅc(OH)-C(H+)=C(HX)+2C(HX)2C.PQÅÞ-:MN=Q>M,àa=712ஹMn(s)+O(g)=MnO(s)5AH.22S(s)+O(g)=SO(g);AH;2Mn(s)+S(s)+2O(g)=MnSO(syAH243ᑣᑡ⊤234Ḅ5()A-AH>C2B-AgAHiCMn(s)+SO(g)=MnO(s)+S(s)!AH=AH-AH222:D-MnO,(s)+SO,(g)=MnSO(s)!AH=AH-AH-AH432113ஹ᝞5CO2onᵬ⏣Ḅâã¨ᓄ.ᑡa·34Ḅ5()A.E2-E15^_Ḅ]ᦔ_B.E3-E15^_Ḅ]ᦔ_C.^_¤]ᙠ´S´ÌæâçèD.éê¨ë-ìàᨵᦔíᑴSïᦔ_14ஹtPQÅðâᨵNIVஹBa2\Na\Fe2\CLஹCO32-,NO3-ñ}k@ÅḄᦪ}஺tòÊó4ôõPQ᪵

4÷ᑖøçèù᝞éúজᵨpHüýKþPQᕈ⏚ឋঝᐭNaOHᨵឋᕡḄᨵᡂঞᐭ⏚⏚ᓄḄAgNCh⁐টBaCLᨵᙠ"ᐭ#$%&KSCN'(⁐)*+ᨬ-./ᙠ012345"6/7ᨵNHJஹFe2+ஹCL9345஺;ᑖ᪆)*+>◤⌕Aᡂ01BCDEFᓽHIJKLM஺A.জঝটB.জঝC.জঝ®®D.ঝঞট15ஹᐵOPQRpH=2Ḅ₝⏚(H2c2O4)RᑡUVW.ḄXA.1L"7H+Y0.02molB.C(H+)=2C(C2O42)+C(HC2O-)+C(OH)4C.$Z[₝⏚Ḅᵯ4]^ᜧpH`aD.ᐭbcpH=2Ḅd⏚⏚ឋ`a16ஹᓄ+ᙠe"ᨵḼghḄiᵨRᑡkiᐵlW.ḄX()⌱⚗ᓄ+ឋqE▭iᵨAA12(SO4)3stᡭNa2cChviwxyzᘤyzB|ᾦᙠ⏚ឋᩩRḄ$vi"ᑴḂC⏚ᐹᨵ⏚ឋ◀$DSO2ᐹᨵឋHᵨO^A.AB.BC.CD.Dஹ⌱⚪(⚪ᒹ5a⚪)17ஹᔠᡂḄᱥJḄᔠᡂV᝞ᡠ

5R.R,¡Ri—NH—R+C1—RNa->+HCl23R
R.CCX'HCOOR,cllcll0XaR1COOR2+R3cH2coOR4”3.>1+R2OHR.ONHR,H(RlஹR2ஹR3ஹR4Y¢ᡈ¤¥)RtR,R,¦§¨Rᑡ©⚪(DBḄᓄ+ª«Y,FḄL᪀®Yফᨵ°ᱥCH2=CHCH2NH2"Ḅ±²³ª«X,ᵫAᡂBḄvi¶·YবঞḄᓄ+¹®Y஺(4)¡টᨵº/Ḅvi▲]vi¼½¾ᐭ¿▾(C5HsN,ÁOᨵ°Â)²ÃÄJḄ᳛ÆÇXo(5)ᨵ°ᱥKᑖ5ÈᡂÉFÊËD¢Æ5ÌᔠRᑡ⌕ÍḄKḄ*ᑖÎ᪀ᨵ3(Ïὃ⇋ÒÎ᪀)஺জ⍗FeCb'Õ⁐ঝÖ×0ᨵËDØ¥0IOH(6)COOdJXº3Ù⌕Ḅᓄ"Ú஺Û×⏣(Ý)sÝ⏣YÞßÆᧇLᔠ¡áâ⌱ã⌕Ḅä°åᑺ,0ᑏJᑴᜓ,ஹ/COOC2HsḄᔠᡂêëo(¡RHC=CHR'ì?஺aெ>RCOOH+RCOOH,RஹR'Yᰦ¥஺ᵨL᪀®⊤ᨵ°ᱥᵨòᜮ⊤ôᓄᐵlòᜮ0õöåᑺsviᩩ)18ஹᡡ᪻⏚Dᙠᨵ°ᔠᡂsᱥ"ᨵḼghiᵨ஺ᵨPùᓄÆᧇᑴᜓD,%ᵫKᑴᜓᨵ°ᱥIḄᔠᡂêë᝞R:OOH0Hû|L„HCNIH+I4n¡—C—H------->—CH—CN——►—CH—COOH§¨Rᑡ©⚪পCḄª«X,IḄᑖ5®Y஺(2)E—FḄvi¶·Y,G"±²³Ḅª«Y(3)A-BḄᓄ+¹®Y஺

6(4)viG-HḄåᑺþᩩX.(5)ᑏ
ᔠᑡᩩḄDḄᑖ᪀,জঝFeCh⁐ঞ᪶"ᐳ$%&'☢)*+1
2:2:3(6)ᑏ
,-./01ᧇᑴᜓHḄᔠᡂ67(ᐸ:;ᑺ=⌱)஺19ஹNa2so3BCDE⁐FG,HIJKᵨMN1ᑺஹ■ῖᑺQ஺RᓄTUVWXYpHḄNa2s03Z[AgNO3Ḅ\ᱥ^_`᝞bc஺bcIdᑴ500mLCeZ[ḄNa2sChজfghijCeklḄNa2s03ᨔ^ᵨnoḄpqrf஺pqr◤noḄ1tBCঝuvJwfxḄNa2s03ᙠz{|}ᓾxᐭᘤA|^ᑣᘤA0C,C(ᘤi)2~3^vCᐭᘤA|ঞer[72cmᜐ^ᦋᵨᜮpqr☢[7ᑗ^^J᎔^᤯ᒴ஺bcIIWXYpHḄNa2sChpH=4ḄAgNChḄ\ᱥ¡▅£ᧇi.Ag2sth0E⁐¤^Y¥r^¥¦lNa2s03ii.AgO,§¨⁐¤^Y¥r^KZ©r2পvpH=8ḄNa2sChᐭpH=4ḄAgNCh|^\E⁐«¬஺Ꮇ®C¯E⁐«¬0Ag2s03Ꮇ®°¯E⁐«¬0Ag2s04Ꮇ®±¯E⁐«¬0Ag2s03²Ags04Ḅ³ᔠᱥ2জᑏ
Ꮇ®CḄ´µ¶·¸ߟঝº
Ꮇ®°ḄK»¼B;ঞc¾Ꮇ®±BᔲᡂÀḄbcÁMBCoফvpH=4ḄAgNCh⌲ÄÅlḄpH=llḄNa2s03|^ÆÇ\E⁐«¬A,ᯠxÉᡂ§¨⁐ᱥk஺0ÊẆXE⁐¤AḄᡂᑖ^j§¨⁐¤_`᝞bc,J~~GOjg⁐⁐জÌÍ(b)ḄᓄT¶·¸0Ag(NH3)2OH+3HCl=AgCll+2NH4Cl+H2O,ᑣ(a)ḄᓄT¶·¸0ঝᡂE⁐«¬AḄ0ÎÏᓄN1^ᑣAḄÐ⌕ᡂᑖB—(ᑏᓄT¸)஺(3)ᵫJwbcKÍ^ÔÕḄÖᙠ×᪵ឋ஺Úc¾^(1)|bcᎷ®CᡂÀ^ÛÜ1(2)|bcḄ\ᱥY¥(1)bcḄᩩBC஺20ஹ᝞ÝBbcÞᑭᵨàZá⏚ᑴj°ÏᓄáWXãḄឋk^äåæᑡç⚪

7(1)éêA|mḄMᵨéêA|ᨵìḄCᜐ┯î_஺(2)éêA|ḄᓄT¶·¸C,¯ḄÏᓄ\ᱥB஺(3)éêB|Ḅðñ,¾ìSO2ᐹᨵo(4)éêC|ᙠóô|Y᧕öÖ^Õ÷Êø
ðùú^1tBo(ᵨ´µ¶·¸⊤ü)(5)éêDḄýḄBWXSO2þÿᵨḄ⌮ឋᑏ(6)EḄḄᓄ஺21ஹ⏒!"#⌕Ḅ%ᧇᔠᡂᨵ*ᱥḄ,-஺2N0(g)+Ch(g)2ClNO(g)AH<()(1)ᙠឤ0ᩩ23ᔣ2Lឤ5675ᘤ9ᐭ0.2moINO;O.lmolChJOmin<=ᑮ?⊝஺ABlOminᑁv(aNO)=7.5xlO-3moi.L-i.min“,ᑣ?⊝ENOḄFᓄ᳛aH஺ᐸJᩩ2KᢝMNᙠឤOᩩ23PQ?⊝”“V"ᡈ“=”)஺(2)\]2NO(g)+C12(g)^-2ClNO(g)Ḅ?⊝`ᦪbᜧdᵨḄef஺(3)gNOhCLᢥᱥjḄklm2
1ᐙᐭopq675ᘤr2NO(g)+CL(g)k=2C1NOAHV0,ABNOḄFᓄ᳛a(NO)s<,ḄNᓄt᝞vᡠx஺NO(g)ḄFᓄ᳛a(NO)ᙠt2“3<,yᑁz{Ḅ%|(4)ᙠᐸ}ᩩ2~<ᔣឤ0Ḅ675ᘤᑖᐙᐭImolCLh2moiNO,:2NO(g)+CL(g)=2ClNO(g)H<0,ᑖᩩ2?⊝

85ᘤ0/࠷5ᘤ-/L?⊝TIv2/333IVTVW444VTVWs55জV32Vᑏ“ᜧ”ஹ“”ᡈ“”ঝ5ᘤIIᓄ?⊝`ᦪK=ঞ5ᘤIVஹ5ᘤVᑖh5ᘤI~mᩩ2M-Os<,ḄNᓄ᝞vᡠx஺h5ᘤI~m5ᘤIVᦋNḄᩩ2;5ᘤVh5ᘤIḄ-Mᑣ5ᘤV=ᑮ?⊝<-OP
Ḅ»ὃ¢ᫀoஹ⌱¥⚪§⚪¨ᨵo⌱⚗ªᔠ⚪«1ஹBூ᪆௃

9A.H2s04ᢵ᡾"#$⌱&⏚()*+,ᦑA┯/0B.ᔣ10%NaOH23ᐭ52%CuSO4NaOH6ᑣ8ᑴᜓ;<ᓄ>?@AᦑBBC0C.DᑴEH2s04ஹEHNO3Gᔠ⏚AIJEK⏚ḄMᐜOP⏚ᯠRᔣSTUVᐭWXEH2s04,ᦑC┯/0D.Y᪆"#2[Y\ḄS᪵^_8`aᐭbcᑺ2ḄᔲᑣS᪵fgᙠbcᑺ2ᦑD┯/0ᦑ⌱iBo2ஹDூg᪆௃AஹlmᜧopqiWrᵯtᦪᵯtᦪvwlmvᜧxrytzᦪ᪶᜜ᵯt᣸}~lmḼytzᦪḄᜧolmᜧoz_Ga>Br>Al>CL⌱⚗A┯/0BஹᐗᕜIHAᐗ⌱⚗B┯/0Cஹ793sBrᔩsBr_ᐗ᪶᜜ᵯt᣸}~ᵯt~⌱⚗C┯/0Dஹ\ᑮឋឋvᐸᨬ£¤<ᓄᱥ¦$ᓄᱥḄ§ឋᓽ§ឋGa(OH)3>AI(OH)3,©ឋvᨬ£¤ª<⏚Ḅ⏚ឋv⏚ឋ£«⏚ᜧ¬£⏚⌱⚗DBC0ᫀ⌱D஺3ஹCூg᪆௃A.°ᵬ2²³6´µ¶·ᑮ¸³¹ᨵḄWX»¼½2¾X¿2ÀÁ»8¾X⏙⏚EÄᦑA⚗BC0B.°ᵬ2¸³6K⏚¶·ᑮ²³WXÅḄÆ´2¾XÇ2ÀÁ»8¾XÆ´ḄÈÄB⚗BC0C.É⏚ʬḄ6Ë2ᒹªgÍggÎÏஹᔾᦈÒ5gVÒÓVÔÒᜧ¬ᔾᦈḄÒᦑC⚗┯/0D.6<ᓄÊÕ$VÒ*ÀÁ<Âឮ×ØÙÚR8᪷ÜÇ2ݳ☢£ßᑨá_ᔲᨵÂÀÁᦑD⚗BC0ᦑᫀCoூ^â௃ᑭᵨåæ¾Â»A⌕èéêëTÍÂìU☢£ÄíᢝWï஺4ஹAூg᪆௃Ḅ⏚§ឋðñ¬2c(H+)c(OHT)Ḅ~¦ᜧoÜᑨá⏚§ឋ஺ூòg௃A.c(H+)=c(OH-)ḄWXᕈ2ឋA⚗BC0

10B.¨ᨵ`03pH=7Ḅ°±²ឋḄB⚗┯´C.`03µ°±Kw=l()P,°±Mo¶ឋC⚗┯´D.¨ᨵ`03c(H+)=10-7mol/L<°±²ឋḄD⚗┯´·⚪⌱A஺5ஹDூ
᪆௃A.ᵫ¹º»Mn(h-¼ᓄ஺-½CL,CIᐗ¿ᓄᔠÀᵫ-1Àᓣ½0ÀFÃᵯÅḄᱥjḄkḄ2ÆᡂlmolC12»FÃᵯŽ2mol,⌱⚗AÇÈB.ᵫᐗ¿ᓄᔠÀ»¨ᨵÉÊÅ˼ᓄÌÊÅÍ˼ᓄ᪷ÏᵯÅBᜫÑឤ2n(Cl)=n(Fe2+),ᓽ2ÓঝÔ9ḄChhFeBnḄᱥjḄklm½1
2,⌱⚗BÇÈC.KMnO4TMnSO4,Mnᐗ¿ᓄᔠÀᵫ+7Àz{½+2À᪷ÏᵯÅFÃÑឤH2O2¼ᐗ¿ᓄᔠÀᓣÂᡂ¼᪷ÏHᐗ¿Ñឤ»ÕᡂÖ⌱⚗CÇÈD.¼ᓄᑺ¼ᓄឋ¼ᓄØᱥ¼ᓄឋᵫঞ»¼ᓄឋMnO4>CL,ᵫঝ»¼ᓄឋCL>Fe3+,ᵫঝ»Fe3+MÚ¼ᓄBis¼ᓄឋBr2>Fe3+,⌱⚗D┯´஺¢ᫀ⌱D஺6ஹDூ
᪆௃A.“ÛÜ”ÛhÖḄmÝMNᑣᑁÞ“ÛÜ”ßà<6MNᦑA┯´B.\âãḄãä=ᑮ1åæ"çᓄEḄÖ½èÖᑣâããäßéᑁÞḄ“ÛÜ”ßêᦑB┯´C.“ÛÜ”ᑁḄÛᑖ½NaCI,ᵫÊÅ᪀ᡂMìᙠNaCIᑖÅᦑC┯´900gD.ãḄ6½0.9g-cm-3,íâÖ1L<ÖḄjk½900g,ᵫᦪm½1
500000,NaCI½18g/mol70Tmol'500000—m°»âãᑁÞNaCIḄîï½c=I஺—=lO^mol-L-1,ᦑDÇÈILᦑ¢ᫀ½Doூñò௃ὃóâÖôõḄᵨö÷âÖÛÜḄᡂᑖஹ¹ºḄᵨ½¢Ḅᐵù“ÛÜ”ᑁḄÛᑖ½NaCLúÊÅᓄᔠᱥ,ᵫÊÅ᪀ᡂü“ÛÜ”ÛhÖḄmÝMNᱯþ«“ÛÜÿ᪀Ḅᑨ஺7ஹCூ
᪆௃

11A.ᔾA⚗B.⏚⏚ឋ!ᓣ#$%&⊝ᔣ)*Ḅឋ+B⚗C.ᔾḄ$%,ᓣ#-./0&⊝,ᔣ)*12pHᓾ456789ᵫ;<=>?ᙠᵯB$%ᦋDEḄᵯB&⊝⌼ᡂHIJC⚗┯LD.<=>?ᙠḼNᵯB&⊝$%ᦋD&⊝)*O1EḄpHPQIJD⚗Rᫀ⌱C஺8ஹBூ
᪆௃⚪VWXY᩽[ᵨ]^ᨵ`aᔠᱥᵬeᵯfgᔣ]^ᨵ`aᔠᱥeᵬᵯhᐙᵯjᳮeᑣemjᵯhnojᳮepᵯ2Y᩽Ḅᵯ᩽qrs᩽Ḅᵯ᩽qrs3+2e-=3r஺ூ
௃A.ᵬeᵯfgᔣ]^ᨵ`aᔠᱥᵯfgᔣY᩽ᩞᧇᑣeᵬᵯhᐙᵯjᳮeemjᵯhnojᳮeA⚗┯LB.pᵯ2᩽᝱ᵯwḄL>.ḄxᵯfQᡂᓃᦑᵯwḄ{⁐D}B⚗C.ᐙᵯ2Li+ᔣ▢᩽)*Li+ᔣaᔠᱥBfᣚC⚗┯LD.pᵯ2Y᩽ᜫᵯfḄᦑY᩽Ḅᵯ᩽qrs-2ne==~(^&^C1HJ.-+2nLi*fnூ௃᧕┯sjᵯh□Bfᔣ᩽)*▢BfᔣY᩽)*ᵯh□Bfᔣ▢᩽)*▢Bfᔣ□᩽)*,⌕஺9ஹBூ
᪆௃ᑖ᪆sAஹ^ᜧᑖfḄᔠ^Bஹ᪷ḄᡂRCஹ᪷⏣Ḅ᪀ᑖ᪆Dஹ᪷ᵬ¡¢ᙠᐝ᯿ᩩ¦7§Q¨©Ḅᱯᑖ᪆஺«sAஹ16.25g¢ᓄḄᱥwḄ®16.25g+162.5g/mol=0.1moLᵫ;¯ᓄ^ᑖfḄᔠ^O1Q

12ᡂḄFe(OH)3^°fᦪ²;0.1NA,A┯LBஹ᪗´µ¶722.4L·ḄᱥwḄ®ImoL¸NArjfᡂḄᓫwᐸ»ᨵḄwfᦪ18NA,B;Cஹ1ᑖf⏣»ᨵ3N½·92.0g⏣ḄᱥwḄ®Imol,ᐸ»ᨵ½·ᦪ3N,\,C┯LDஹᵬ¡¢ᙠᐝ᯿ᩩ¦7§Q¨©QᡂḄᓴ©¿,ÀÁO1QᡂḄCH3aᑖfᦪ²;1.0NA,D┯L஺Rᫀ⌱B஺Âs⌱⚗D᧕┯Ã⌕,ÄÅᵬ§Q¨©2Æ;Çᵫ·¨©ÈN¯jfÉᨵÊĘ̈©ᐸPᱥÍÎÏᩖ9¡mÑ¡¯ḄÒᡂÓᐰ,Õ஺10ஹCூ
᪆௃AஹÖ²×⌮Ù᳛ᙳÖ²&⊝ᔣ⌮Üᔣ)*A┯LBஹÖ²×⌮Ù᳛ᙳÖ²&⊝ᔣ⌮Üᔣ)*B┯LCஹÖ²×⌮Ù᳛ᙳÖ²Ù᳛Ö²ḄÝ%Þᜧ&⊝ᔣ⌮Üᔣ)*)*ßÙ᳛⌲á+ᜧCDஹÖ²×⌮Ù᳛ᙳÖ²Ù᳛Ö²ḄÝ%Þᜧ&⊝ᔣ⌮Üᔣ)*)*ßÙ᳛⌲á+ᜧ⌮Ù᳛⌲áÖ²D┯Lᦑ⌱C஺11ஹDூ
᪆௃âᐗ⏚H2XäNaOHᐜ§QH2X+OH=H2O+HX-,ᯠç§QHX-OH=lhO+X/ூ
௃A.MÒᐭ20.0mLNaOHḄwrNaHX,?ᙠHX-ḄᵯBéᡠë12c(Na+)>c(HX),ìḄᡠëC(HX-)>C(HX),ᦑA2B.PÒᐭ40.0mLNaOHᡠëwrNa?X,?ᙠwfíឤc(OH)=c(H+)+c(HX)+2c(HX),2ᓽC(OH-)-C(H+)=C(HX-)+2C(HX),ᦑB2C.MH)=_^_,eÊX÷Ḽ¯ᓄÒᐭMஹNஹPஹQḄឋ+ᑣc(H+)Ö²ᡠëc(HX)c(HX)c(H)c(H)r(X2')â-:MN=Q>M$%ýXþÿ
Ḅᵯ⊝ᦪᡠ
aḄᦑD┯ᦑᫀD„

13ூ௃ᵯ!"#$ᜧ&'(⌕ᢕ+,-⊝.ᵯ⊝/01Ḅ⊝ᢕ,-!2.2ᵯḄᵯ/01Ḅ3!2Ḅ4ᑨ6Ḅ⏚8ឋ:;'(஺=>?@ᐵB⌕CDᵯ₹Fឤ@ஹᱥᧇFឤ@/KFឤ@ḄᮣMNᵨ஺12ஹDூ
᪆௃A.PQRSTUVWXYTUXYTUZ[&W0,AH<0,ᦑA┯2B.TUX\Y]^_`aᑨ6/ᜧ&ᦑB┯,Mn(s)+C>2(g)=MnO2(s)AH®*S(s)+O(g)=SO(g)5bঝজ-ঝf.Mn(s)+SO(g)=MnO(s)+S(s),᪷hij:2222
kfMn(s)+SO2(g)=MnO2(s)+S(s)AH=AH_ᦑC┯D-Mn(s)+O(g)=MnO(s)5AHজ22S(s)+O(g)=SO,(g)5AH,®2Mn(s)+S(s)+2O(g)=MnS0(s)5AH3ঞ24᪷hij
kঞ-জ-ঝf.MnO2(s)+SO2(g)=MnSOMs)AH=AH3-AH?-AHiᦑD4ᦑ⌱D஺13ஹDூ
᪆௃AஹᓄoTUḄYᦔU?WTUᱥ/qᱥḄr]stTUᱥḄr]uWqᱥr]ᡠTUXYᡠTUḄYᦔU3EI-E2,A┯BஹᓄoTUḄYᦔU?WTUᱥ/qᱥḄr]stᡠTUḄYᦔU3Ei—E2,B┯CஹvTUTUᱥḄr]uWqᱥr]ᡠTUXYw3XYTUᙠyz{|}
~r:;C┯DஹRᓄ3ySᵬ⏣ᧇRᓄ/Sᓄᵬ⏣/ḄTU[ᨵᦔᑴyD4஺ᫀ⌱D஺14ஹBூ
᪆௃ᵫজᕈ⏚ឋ|CO3,ᵫঝᐭ]NaOHqᨵឋSᕡḄSᨵᡂNH4+ஹFe2+,ᵫW⏚ឋᩩ¡{NCVஹFe?+|rᜧ]ᐳ¤ᑣ|NCV,᪷hᕈᵯឋ}
C1;ᵫঞᐭ¦⏚⏚ᓄḄAgNChq§⁐Ctᵫটª]BaCh«ᨵqᙠ

14!"ᐭ$%&'"KSCN()*+⁐()!-Fe2+᪷/01ᑖ᪆45()!65-NHJஹFe2\஺9:◤<ᡂজঝ?ᫀ⌱B஺15ஹBூC᪆௃A⌱⚗c(H+)=0.01mol/L,1L()!-H+F0.01mol,ᦑA┯IB⌱⚗᪷/ᵯ₹LឤNᑮC(H+)=2C(CO42)+C(HC2O4)+C(OH),ᦑBQ42C⌱⚗"%RST⊝QᔣWXYZ[\]^_₝⏚ḄᵯZ]cᜧ()pHcᜧᦑC┯ID⌱⚗"ᐭefgpH=2Ḅh⏚()⏚ឋjkᦑD┯I஺l0ᡠ1?ᫀFB஺ூno௃₝⏚pqᐗs⏚tpH=2,YZ[\]uvᐗ⏚wᐵ᪷/pHyzNc(H+)=0.01mol/L,{|}~᧕c(qᐗ⏚)=().01mol/L,᝞p⏚c(H+)=0.02mol/L,ps⏚ᑣc(H+)vO.Olmol/L஺16ஹCூC᪆௃AஹᘤpᑭᵨAL(S()4)3_ᡭNaHCCh()ᦑj⌱ABஹ!ᵨᾦᙠឋᩩḄ%Cᑴ¡Ḃᦑj⌱BCஹ£⏚Ḅ⏚ឋᜧ¤¥⏚ᑭᵨ£⏚u¥⏚┛◀%¨ᦑ⌱CDஹSChᐹᨵ«¬ឋtᵫ¤SOzᨵ:ÀSO2jÁᵨ¤ÂÃc¬ᦑj⌱D?ᫀ⌱C஺qஹ®⌱¯⚪(±⚪ᒹ³5_⚪)CH,CH«CH,11'17ஹ3-$-1-´µ¥¥ÄÅÆÇÈOCHCH-CH1/CH.CH\].CJ!(>H<ÉÊË*ឋÁuটḄᱥHC1Î!

15¬®¯°fᑮCIL-CHCM
ஹ1h᪷hCḄᑖK@³TUᩩ¡aTUঝ´⚪¶·¸Ḅ¯°TUaCCHjaUCOOCH,HC=CHCHN'(CஹDᑖK@¹ᔠEḄ¹᪀¼@ᑖ᪆TUঞ⚪¶·¸Ḅᡂ¾TUaD2;CHJCHJCOOCH,CHjCH-CHi;D´¿ḄTUᡂE,'(E/GḄ¹᪀¹ᔠTUᩩ¡ᑖ᪆ÀqᱥFḄ¹᪀COOCIh0Á'GஹJḄ¹᪀'GQHK—CH2-2-C௃´¯°TUᡂJ,hÃᑖ᪆஺OூÄ௃(1)BC1CH2cH=CH2,ᓄoÅÆ3-Ç-1-ÈÉ'(E/GḄ¹᪀¹ᔠTUᩩ¡ᑖ᪆ÀqᱥFḄ¹᪀ÒcHGCH,CH-CH,1I*'ᦑÊ.3-Ç-1-ÈÉOO(2)᪷hËrÌḄ¹᪀ᑖ᪆ᨵÍᱥCH2=CHCH2NH2ḄËrÌᨵÎÏ/®'(A/BḄ¹᪀[ᓄavTU¯°TUᦑᫀ.ÎÏ/®¯°TU;CUCH.CHAXXX'H,((3)᪷hÑÒᑖ᪆TUঞḄᓄoÓÔ@H\CIIOIKᦑCHrCH.CCXKHICCXK'H,()CHCfl—CHᫀ.H<11(II\(H.CH.axxn('(MXH(4)TUট¯°TUᡂᨵÍᱥḄÕÖᡂHCL×Øỏᕈ8ឋQHC1´/TUÚ⊝4ᔣÜÝ,ßuJḄq᳛ᦑᫀ.Øáâ8ឋrQTUটḄqᱥHC1´/TUÚ⊝4ᔣÜÝßuJq᳛CHCH-CH.I2L'(5)FQᑖK@C8H13NO,ᑣKḄᑖK@CH„NO,জ⍗FeCbâä⁐ᑣ¹᪀ᨵåæ8O®ঝç¾Ñᨵ,-¯°®}-OH,ᑣè}-ᵫ2-CéK6-HéK1-NéK᪀ᡂḄ¯°®ᐸ¹᪀ᨵ-CH2cH2NH2ஹ-CH2NHCH3ஹ-CH(CH3)NH2ஹ-NHCH2cH3ஹ-N(CH3)2ᐳ5ë,¯°®ḄìíᐳᨵîஹÀஹÁïëðñᡠKḄÕᑖò᪀ᨵ3x5=15ëᦑᫀ.15

16ó6õᵫ⚪¶·¸aᵫTUfᑮó᜛ó,00cù'0ᵨ⏚ឋuú⏚ûRᓄḄü⏚üOH⏚Qý⏣´¿ᓄTUfᑮ;Gᵫéᧇÿ
ᑣᔠᡂIINῃ2Hsூ௃!⚪Ḅᐵ%&'!()ẚ+'ᱥ-!.ᑨ0᪶2345ὃ஺89ᙠ;<ᑡ>?ᐵ<@ᨵBᑖᱥ-DEFDEᱥGGᡂ5H“ᑖᦣ”ḄὶM஺N'ᵫPᧇMᔠᩩSTᔣ>?VᱥWN'XVᱥMᔠᩩS⌮ᔣ>?PᧇWN'X@ZVᱥ[ᔣ\]>?^⚪_⌕ᢕbcẠEeMᔠfgh34ᑖ᪆ஹὶkஹl᯿ஹnoᵨஹq᯿ᩩS>[Mr஺⚪Ḅᐵ%&⌕s៉ᚗḄᔜwx
ᱥZḄyᓄᐵ<{|⌕}~ᱥ-Ḅx⌕}~_Ḅᑖ@ஹஹஹᓴPᦪ'ᨵᱥlᑖ-Ḅxwᦪஹ-ḄᦋGGᡂ⚪Ḅ)ẚ+஺CHCHBrᝯᡈ_>CH3cH20H9>CH3cHO-Öf32HCH3CHCOOHூ᪆௃CHCh᪷Aᵬᵬᙠᐝ᯿ᩩS
]Ḅ
ᡂB,¢£80¦Bᙠᓄ§¨©0H@
ª
ᡂC,ᑣC஺,᪷ghDᔆAH-COOH¬®
¯ᡂ
ᡂE,E1,2-OH9°±¬²,Eᙠᓄ§¨©@ª
ᡂF,F³H1”11ஹ³´11"µ¶┶⏚¹¨©ᓄ
ᡂ6,6?

17OHonOHGuY×"ᡂNᑮH,HF-COOHuÎØᓄᡂI,"ᡂᑖ᪆C?஺CHCHCOOH5CHjCHCOOH3ூÚC௃CHO1^1?প᪷/01ᑖ᪆CF6ÜÝFÞᵬàḄᑖ[¼FCuHioOsOOH9(2)E-FF1,2-qá´âᙠYãᓄä()!Î%CᡂÉḄG(,,II.)!åÁæCH3CHCH2OHCCOOHᨵçÇஹᢈÇ;(3)᪷/01ᑖ᪆ATBḄᓄ~êë¼F+2CU+2HC1(4)G-HFìÇḄ"ᡂíᑺïᩩFH“Ni,"ð;OHমDF0AH-COOHজÁÎñòóô½᪀!õᙠàÇঝuFeC13()*ö⁐óô-ᨵ÷øÇঞ᪶rúᐳüYýþ☢
1
2:2:3,ᔠᩩḄDḄᑖ᪀ᨵOH(6)ᧇᑴᜓH(|)◤⌕᪷!"#$ᑴᜓDḄᑖ᪆&'ᔠ⚪$)*ᑴᜓ,CHjCHCOOH,-◤⌕✌ᐜᑴᜓCH3cHO,&ᵫ1234ᡂ⏣⏣7ᓄ4ᡂ9,-ᔠᡂ:;OHHCNCHCHBr*'ᔙA>CH3cH20H஺ᨌḄ>CH3cHO32??CHjCHCOOH19ஹH◀J✄2$Ḅ7L■NOP⏚RS7ᓄ500mLTUVWXஹYᴻ[SO2+2Ag+=Ag2SO33Na2sO3S⏚ᓄḄN(h•7ᓄᡂNa2so4,Na2sCh]AgNCh^A_`4ᡂAg
2sChabcdefgᐭiUNa2sCh^A(ᡈᔣmn$opqgNa2s஺3^A)AgO+4NH3•HO=2Ag(NH)2OH+3HOᡈ2232Ag2O+4NH+H2O=2Ag(NH)2OHAgOHNa2sO3^Aqgstu(ᡈᵨUu)^A⏚wឋu(ᡈyzu33)ூ3᪆௃}~ᱥḄUyzḄ^A,

18জ^3Na2so3ᨔ᧕S^A$^3Ḅ7L7ᓄᦑ◤ঝA}~ᱥḄUyzḄ^A◤⌕ᵨTUVA◤⌕WXYᴻ[nupHḄNa2s஺3^A]pH=4ḄAgNCh^A_`ḄᱥজᎷ]OP⏚᪷_`4ᡂOP⏚ঝὃ⇋gᐭḄ⏚ឋḄ⏚^Aᐹᨵ7ᓄឋ¡OP⏚7ᓄᡂP⏚ঞᵫ£Ag2sCh^£¤UNa2s03^A&gᐭNa2sCh^A¥^A$ᔲᨵAg2s஺3ফজAgO§¨⁐d]ª2_`4ᡂAg(NH)2OH3H2023ঝ«¬7ᓄ_`ᑖ᪆®ᓄᔠ¯u°ᑨ²AḄᡂᑖ(3)(1)$(2)$$^AḄqgstu^A⏚wឋu஺ூ௃জ^3Na2s03ᨔ᧕S^A$^3Ḅ7L7ᓄᦑ◤■NOP⏚RS7ᓄঝA}~ᱥḄUyzḄ^A◤⌕ᵨ500mlḄTUVA◤⌕WXYᴻ[2~3³পজᎷ]OP⏚᪷_`4ᡂOP⏚SO2-+2Ag+=Ag2sO3;3ঝ¡pH=8ḄNa2sO3^AqµpH=4ḄAgN(h^A$⏚ឋ^A$¶ᙠ¸¸⏚᪷¹º£⏚ᐹᨵ7ᓄឋ&»¼¡OP⏚᪷7ᓄᡂP⏚᪷ঞ.Ag2s½⁐du^£2^£¤UNa2s03^Aᦑ&gᐭ¤UNa2sCh^A¾ᔲop^3¿op^3ÀᑖÁÂᎷÃᡂÄ(2)জAg2O,§¨⁐du^£2&]yª2_`_`aAg2O+4NH3•H2O=2Ag(NH3)2OH+3H20;ঝ¡pH=4ḄAgNCh^A⌲qqµiUḄpH=llḄNa2sCh^A$ᵫ£OP⏚᧕^£OP⏚Rᦑ4ᡂḄ½⁐abuOP⏚^AᕈwឋÇuP⏚ᙠwឋᩩÈÉ᝞ª2_`&4ᡂ¸7ᓄ½⁐abAAgOHবপ¡pH=8ḄNa2sCh^AqµpH=4ḄAgNCh^A$ফ¡pH=4ḄAgNCh^A⌲qqµiUḄpH=llḄNa2so3^A$Íγ&¾Ïqgstu(ᡈᵨUu)ᡠÑÒ^A⏚wឋu(ᡈyzu)஺20ஹÓ⊝LÕAs!ÈJÖWV$ḄAפØTᘤÚÛḄ2/3Cu+2H2sCWy)AC11SO4+2SO2T+2H2OCuSOKMnCh^AÜ⁐(Ý⁐°ᡂÞ⁐)ឋ42S2+O+2HO=2S+4OHßà^AÜ⁐áᐵãᑖAäᧅḄæçèéê⏀ìí^A°ᡂà⁐î2Ü⁐22SCh+Br2+2H2O=2HBr+H2sூ᪆௃(1)ï~A$mḄðᵨÓ⊝LÕAs!È᪷J✂WVᵨòᑣJ✂WV$ᡠôõAu»×¤ᐸTḄ2/3,Çu»e£1/3,#$÷øפᐸTḄ2/3஺ùᫀÓ⊝LÕAs!ÈJÖWV$ḄAפØTᘤÚÛḄ2/3஺

19(2)ï~A$û]yP⏚ᑴcü7ᓄPý4Ḅᓄþ_`ÿ
Cu+2H2s04()&C11SO4+2SO2T+2H2஺,Cuᵫ0+2ᜫᵯᓄᓄᱥCuSCh;ᫀCu+2H,SO4)&CUSO4+2SCM+2H,O
C11SO4;(3)AᡂSO2!"SO?ᐹᨵ%&ឋ!"()BḄ⏚ឋKMnO,-.ᓄ%&KMnO,44-/⁐(2⁐ᡂ3⁐)4ᫀKMnOa,-/⁐(2⁐ᡂ3⁐)4%&ឋ4(4)CNa2s,-S*ᐹᨵ%&ឋ56᧕8!Chᓄᡂᓫ:S,;<=>?@ABCᵨEF
⊤H2S2+O+2HO=2S1+4OH422ᫀ2s2-02+2@0=2S1+4OH(5)DḄIḄJKSO2LMNOᵨḄPQឋR⌮ḄTUVOWAXMN,-/⁐Yᐵ[ᑖ-]ᧅḄ_`abc⏀efgh,-ᡂN⁐஺(6)ᡂḄSO2iᐭᑮESO2Llm.ᓄ%&nm,-/⁐.ḄᓄoF
SO2+Br2+2H2O=2HBr+HSO42ᫀpm,-/⁐4SO2+Br2+2HO=2HBr+H2SO4221ஹ75%>stuvt2wᑮx⊝,t2~t3zuvᓣ|x⊝⌮ᔣ~NOᓄ᳛72ᵨᓄᑺ6Mpaa(2)21;ὃ¦§ᓄox⊝¨ᦪḄ©ª«hstuvx⊝ᔣFᔣ~ᓄox⊝¨ᦪ¬ᜧ©®ᵨ¯°stuv4(3)ὃ±²ᱯᑡ&ᳮt2;¶NOḄᓄ᳛ᨬᜧ¸¹wᑮx⊝ᓽ0t2;¶ᔣFᔣFᔣ«ht2;¶Yuvᓣ|x⊝ᔣ⌮Fᔣ~NOḄᓄ᳛st4(4)ὃᓄox⊝¨ᦪḄஹ±²ᱯᑡ&ᳮজT3>T1,ᙠTIḄ»Ạ½ᓣ|uvᑮT3,Fᔣ«hx⊝ᔣ⌮FᔣC1NOḄst¾III¿I6ᘤC1NOḄÁÂÃIII6ᘤḄ"ÄI6ᘤ©V3<2L
ঝ2NO(g)+CL(g)d2ClNO(g)ÅÆ210ᓄ2xx2x2x2x⊝
2-2x1-x2xI6ᘤwᑮx⊝;,CINOḄÁ2/3,©ᨵ------=-Éx=0.75,3-x3

20᪷ᓄ¾¿⊝9ᦪḄÁÂK==72,ᓄ¾¿⊝9ᦪÃÄÅÆḄÇÈÉᘤII@ÅÆÉᘤIḄÅÆË¢£Éᘤn@ᓄ¾¿⊝9ᦪ72ঞ᪷ÍIVÎIᐜÐᑮᓄ¾¿⊝,ÙÚIVḄᓄ¾Û᳛ÎIÝÐᑮ¿⊝&IVÞIÕÖÙÚߢÃÇÈᓄ¾Û᳛{ÇÈᓄ¾¿⊝ḄoࢣᦋḄáâᩩS&ãᵨäᓄᑺ¦æVÉᘤ@ὑCLḄᱥ-ḄymoLᑭᵨPV=nRT,éê_F©ÌgÍ,Ðᑮ¿⊝Ò;´=,Ô[y=3—P/3,VÉᘤÕÖᜧØI,¿⊝9x26x2usqᔣTëᔣ34,y>0.75ᓽ3—P/3>0.75,ÔP<6.75,᪷ÕÖ_ZḄᐵ<>[PḄî&6Mpa[ÅÆüZḄᐵ<ᯠÒþÿ
ᑮ⊝ᑮy=3—P/3,6x2Z25ÍVᘤḄIᘤᜧ⚪ᜧᓄ⊝ᔣᔣ!ὑ#$Ḅ%ᜧᓽy>0.75,ᨬ(PḄᨬᜧ)஺